SF Prep Notes
02 MP Police SI Prelims 2026 — Master Notes 🕒 Updated 2026-09-30
MP Police SI 2026 Prelims English 35 Official PYQs (2025)

🧪 Chemistry

Matter, atomic structure, periodic table, chemical reactions, acids-bases-salts, metals-non-metals, carbon compounds, soap, polymers, fuels, fertilisers, biomolecules, noble gases & radioactivity — NCERT 6-12 level, planned around the 2025 paper.

📌 0. Exam Pattern & 2025 Analysis (2 min read)

  • MP Police SI Prelims has 10 Science questions: Physics 4 + Chemistry 3 + Biology 3. So Chemistry = 3 questions in every shift.
  • Analysis of the 36 Chemistry questions in the official 2025 paper (16–21 Jan 2026, 12 shifts):
    • Atomic structure + Periodic table — the most (~14 questions): amu, isotopes, valency, quantum numbers, spectral series, electronegativity, dipole moment.
    • Polymers (~6): Teflon, nylon, polycarbonate, elastomer, starch plastic, wool-silk.
    • Soap / micelle (~3), Surface chemistry & kinetics (~5), Biomolecules & drugs (~4), d-block (KMnO₄) (~2), organic naming (~3).
  • ⚠️ The level is not limited to Class 10 — many questions came from NCERT Class 11-12 concepts. That is why every topic on this page also has "Advanced (11-12) quick facts".
💡 Strategy: First make the basic tables (formulas, ores, alloys, pH, polymers) solid — they give direct marks. Then read the PYQs: MPESB asks concept-based "why" questions (e.g. "Why is Teflon chemically resistant?").

📌 1. Matter, Mixtures & Colloids (6 min read)

1.1 States of Matter

  • Anything that occupies space and has mass = Matter. Three common states: Solid — fixed shape & volume; Liquid — fixed volume, no fixed shape; Gas — neither shape nor volume (most compressible).
  • Plasma = 4th state — very hot, ionised gas. Found in the Sun/stars and inside neon signs.
  • Bose-Einstein Condensate (BEC) = 5th state — at very low temperature. Named after Indian scientist Satyendra Nath Bose and Einstein.
  • Attraction between particles: Solid > Liquid > Gas. Diffusion is fastest in gases.

1.2 Change of State

ProcessWhat happensExample / Fact
Melting / FusionSolid → LiquidMelting point of ice is 0°C (273.15 K)
BoilingLiquid → Gas (throughout the liquid)Water at 100°C (at 1 atm)
EvaporationLiquid → Gas (only from the surface, at any temperature)Causes cooling — water in an earthen pot (matka), sweat
SublimationSolid → directly GasCamphor, naphthalene, ammonium chloride, iodine, dry ice (Dry ice = solid CO₂)
CondensationGas → LiquidWater drops on the outside of a cold glass
  • Evaporation increases with: temperature ↑, surface area ↑, wind ↑, humidity ↓.
  • Pressure cooker: higher pressure raises the boiling point of water → food cooks faster. On mountains air pressure is low → water boils below 100°C → food takes longer to cook.
  • Adding salt to water raises the boiling point and lowers the freezing point (that is why salt is used to melt ice on roads).

1.3 Physical vs Chemical Change

Physical ChangeChemical Change
No new substance is formed; usually reversibleA new substance is formed; usually irreversible
Ice melting, water boiling, salt/sugar dissolving, glass breaking, making a magnet, wax meltingRusting of iron, curd from milk, cooking/digestion of food, burning of paper/wax, bursting of crackers, photosynthesis
⚠️ Exam Trap: A burning candle involves both changes — melting of wax (physical) + burning of wax (chemical).

1.4 Pure Substances & Mixtures

  • Element: only one kind of atom — Fe, O₂, Na. Compound: elements chemically combined in a fixed ratio — H₂O, NaCl, CO₂ (properties differ from those of its elements).
  • Mixture: no fixed ratio; components keep their own properties.
    • Homogeneous: uniform throughout — salt solution, air, alloys (brass), soda water.
    • Heterogeneous: — sand + water, oil + water, cornflakes-in-milk.
  • Solution — smallest particles, no Tyndall effect. Suspension — large particles that settle down (muddy water, chalk-water). Colloid — intermediate size, particles do not settle, show the Tyndall effect (scattering of light — sunbeams coming through trees in a forest).

1.5 Types of Colloids (learn the examples)

TypeWhat in whatExamples
EmulsionLiquid in liquidMilk (fat in water), butter (water in fat), cold cream
AerosolLiquid/solid in gasFog, clouds, mist (liquid in gas); smoke (solid in gas)
FoamGas in liquidShaving cream, soap lather
GelLiquid in solidJelly, paneer/cheese, butter
SolSolid in liquidPaint, ink, mud
  • Breaking an emulsion (Demulsification): by heating, freezing or Centrifugation. A substance that keeps an emulsion stable = emulsifier (e.g. soap, protein).

1.6 Separation Techniques

MethodWhen usedExample
FiltrationInsoluble solid + liquidTea leaves from tea
CentrifugationVery fine particles; by spinning fastCream from milk (dairy), blood/urine tests, washing machine drier
ChromatographySeveral colours/substances dissolved in the same solventColours in ink, identifying drugs (forensic)
DistillationMiscible liquids with a large difference in boiling pointsAcetone + water
Fractional DistillationSmall difference in boiling pointsSeparating gases from air, petroleum refining
Separating funnelImmiscible liquidsOil + water
SublimationWhen one component sublimesSalt + ammonium chloride / camphor
CrystallisationTo get a solid in pure formPure salt from sea water, alum (phitkari)
⚠️ Vyapam Alert (Exam Traps):
  • Milk = emulsion (fat in water); butter = emulsion (water in fat). Fog/clouds = aerosol.
  • Dust particles shining in a sunbeam = Tyndall effect (a property of colloids). A true solution does not show the Tyndall effect.
  • Camphor, naphthalene, NH₄Cl, iodine, dry ice = sublimation.
🎯 Official PYQ (MPESB SI Prelims 2025):
Q1. Emulsions can be divided into their constituent liquids by:MPESB SI Prelims 2025 — 18 Jan 2026, Shift 1
(1) Centrifugation
(2) Adding more emulsifier
(3) Adding a lyophilic colloid
(4) Cooling to 0°C
Correct answer: (1) Centrifugation
Explanation: An emulsion is broken by heating, freezing or centrifugation (demulsification). Adding an emulsifier or a lyophilic colloid does the opposite and makes the emulsion stable. Just cooling to 0°C (without freezing) is not enough.
✍️ Practice MCQs (self-made, not PYQs):
P1. On heating, camphor turns directly into vapour. This process is:
(A) Evaporation
(B) Sublimation
(C) Condensation
(D) Boiling
Answer: (B) Sublimation — the solid turns directly into gas.
P2. Which method is used to separate cream from milk?
(A) Distillation
(B) Chromatography
(C) Centrifugation
(D) Sublimation
Answer: (C) Centrifugation
P3. Which of the following is a chemical change?
(A) Melting of ice
(B) Sugar dissolving in water
(C) Milk turning into curd
(D) Breaking of glass
Answer: (C) — a new substance (lactic acid) forms in curd, and it cannot turn back into milk.

📌 2. Atomic Structure (8 min read) — most questions in 2025

2.1 Sub-atomic Particles & their Discoverers

ParticleChargeDiscoveryNote
Electron−1J.J. Thomson (1897, cathode rays)Mass about 1/1836 of a proton — the lightest
Proton+1E. Goldstein (1886, canal rays) observed positive rays; name/identification by RutherfordIn the nucleus
Neutron0 (neutral)James Chadwick (1932)In the nucleus; ordinary hydrogen (protium) has no neutron
Nucleus+veRutherford (1911, α-scattering)Almost the entire mass of the atom is in the nucleus

2.2 Atomic Models

  • Dalton (1808): atom is indivisible — later proved wrong.
  • Thomson model: "Plum pudding / watermelon model" — a positive sphere with electrons embedded in it.
  • Rutherford's α-particle scattering experiment (Gold foil experiment): α-particles (+ve) were fired at a thin gold foil:
    • Most passed straight through → most of the atom is empty space.
    • Some were deflected through large angles → there is a small, heavy, positive nucleus at the centre that deflects α-particles by repulsion.
    • Very few (NCERT: about 1 in 12000) bounced straight back.
    • Drawback: revolving electrons should lose energy and fall into the nucleus — it could not explain stability.
  • Bohr model (1913): electrons revolve in fixed orbits/shells K, L, M, N; each shell has a fixed energy. Max electrons in a shell = 2n² (K=2, L=8, M=18, N=32).

2.3 Atomic Number, Mass Number, Isotopes (Z, A, Isotopes)

  • Atomic number, Z = number of protons (= electrons in a neutral atom). Concept: Henry Moseley (1913).
  • Mass number, A = protons + neutrons. Neutrons = A − Z.
  • Isotopes: same Z, different A → different neutrons. Chemical properties are the same (because electrons are the same). Hydrogen has 3: Protium ¹H (0 neutron), Deuterium ²H / D (1 neutron — heavy water D₂O), Tritium ³H (2 neutrons, radioactive). Carbon: C-12, C-13, C-14 (C-14 radioactive — carbon dating). Chlorine: Cl-35, Cl-37.
  • Isobars: same A, different Z — ⁴⁰Ar and ⁴⁰Ca. Isotones: same number of neutrons.
  • ⚠️ Fluorine has only one stable isotope (F-19) in nature (monoisotopic element); so in a "which has no isotopes" type question, the answer is Fluorine (Hydrogen, Carbon and Chlorine all have several isotopes).

2.4 Atomic Mass Unit & Mole (amu & Mole)

  • Atomic mass unit (amu / u) = 1/12 of the mass of one C-12 atom ≈ 1.66 × 10⁻²⁷ kg. Atomic mass is written in this unit (not in kg/gram).
  • Mole: 1 mole = 6.022 × 10²³ particles (Avogadro number). Mole = SI base unit (amount of substance).
  • Molar mass: H₂O = 2(1) + 16 = 18 g/mol; CO₂ = 12 + 2(16) = 44 g/mol; NaCl = 23 + 35.5 = 58.5 g/mol.

2.5 Valency

  • Valency is decided by the electrons in the outermost shell (valence shell) — how many electrons an atom will give/take/share to complete 8 (octet).
  • Outer electrons 1-4 → valency = the same number; 5-7 → valency = 8 − electrons. Examples: Na (2,8,1) → 1; Mg → 2; Al → 3; C → 4; N (2,5) → 3 (valency of N in NH₃ is 3); O (2,6) → 2; Cl (2,8,7) → 1; noble gases → 0.

2.6 Advanced (11-12) quick facts — Quantum numbers & Spectrum

Quantum numberWhat it tells
Principal, nShell, size and energy
Azimuthal, lShape of the orbital — s (spherical), p (dumbbell), d (double dumbbell)
Magnetic, mOrientation (direction) of the orbital in space
Spin, sSpin of the electron: +½ or −½
  • Rules: Aufbau (the lower-energy orbital fills first), Pauli (max 2 electrons in one orbital, with opposite spins), Hund (first one electron in each orbital, then pairing).
  • Hydrogen spectrum series (the level at which the falling electron ends):
    Lyman → n = 1 (UV) | Balmer → n = 2 (visible) | Paschen → n = 3 (IR) | Brackett → n = 4 (IR) | Pfund → n = 5 (IR).
    Trick: "Lucky Boy Played Badminton Properly" = 1, 2, 3, 4, 5.
⚠️ Vyapam Alert (Exam Traps):
  • In isotopes the neutrons differ — protons/atomic number/chemical properties are the same.
  • Orbital shape = azimuthal (l); orientation = magnetic (m) — do not mix them up.
  • Atomic number concept = Moseley; Neutron = Chadwick; Electron = Thomson; Nucleus = Rutherford.
  • In Rutherford's experiment, deflection of α-particles = repulsion by the positive nucleus (not collision with electrons).
🎯 Official PYQs (MPESB SI Prelims 2025):
Q1. Which of the following is the CORRECT unit of atomic mass?MPESB SI Prelims 2025 — 16 Jan 2026, Shift 1
(1) kg
(2) gram
(3) amu
(4) mol
Correct answer: (3) amu
Explanation: Atomic mass unit = (mass of a C-12 atom) × 1/12. An atom is so light that writing its mass in kg/gram is not practical; mol is the unit of "amount", not of mass.
Q2. In Rutherford's α-scattering experiment, why were some α-particles deflected through large angles?MPESB SI Prelims 2025 — 16 Jan 2026, Shift 1
(1) Due to collisions with electrons
(2) Due to repulsion by the positively charged nucleus
(3) Due to magnetic effects in the foil
(4) Due to uneven distribution of mass
Correct answer: (2)
Explanation: α-particles are positive; when they pass near the small, heavy, positive nucleus, they are deflected through large angles by repulsion. Electrons are so light that they cannot deflect α-particles.
Q3. Which of the following quantum numbers determines the shape of orbitals?MPESB SI Prelims 2025 — 17 Jan 2026, Shift 1
(1) Principal quantum number (n)
(2) Azimuthal quantum number (l)
(3) Magnetic quantum number (m)
(4) Spin quantum number (s)
Correct answer: (2) Azimuthal (l)
Explanation: l = 0 (s, spherical), 1 (p, dumbbell), 2 (d). n → size/energy, m → orientation, s → spin.
Q4. The valency of an element is determined by:MPESB SI Prelims 2025 — 17 Jan 2026, Shift 1
(1) The number of protons in the nucleus
(2) The atomic mass of the element
(3) The number of electrons in the outermost shell
(4) The number of neutrons
Correct answer: (3)
Explanation: Chemical bonding happens only through the valence (outermost) electrons, so valency is also decided by them.
Q5. Which spectral series is related to transitions ending at n = 3?MPESB SI Prelims 2025 — 19 Jan 2026, Shift 1
(1) Lyman
(2) Balmer
(3) Paschen
(4) Pfund
Correct answer: (3) Paschen
Explanation: Lyman n=1, Balmer n=2, Paschen n=3, Brackett n=4, Pfund n=5.
Q6. The valency of nitrogen in NH₃ will be _____.MPESB SI Prelims 2025 — 20 Jan 2026, Shift 1
(1) 1
(2) 2
(3) 3
(4) 5
Correct answer: (3) 3
Explanation: N (2,5) needs 3 electrons to complete its octet → 3 bonds with three H atoms (NH₃).
Q7. Isotopes of the same element differ in:MPESB SI Prelims 2025 — 21 Jan 2026, Shift 1
(1) Chemical properties
(2) Number of protons
(3) Number of neutrons
(4) Atomic number
Correct answer: (3) Number of neutrons
Explanation: Isotopes: same Z (protons), different mass number — the only difference is in neutrons.
Q8. Which of the following elements does not have isotopes?MPESB SI Prelims 2025 — 21 Jan 2026, Shift 2
(1) Fluorine
(2) Carbon
(3) Hydrogen
(4) Chlorine
Correct answer: (1) Fluorine
Explanation: In nature, fluorine occurs only as one stable isotope (¹⁹F) (monoisotopic). Carbon (C-12, 13, 14), Hydrogen (protium, deuterium, tritium), Chlorine (Cl-35, Cl-37) — all have isotopes.
✍️ Practice MCQs (self-made, not PYQs):
P1. Who discovered the neutron?
(A) J.J. Thomson
(B) James Chadwick
(C) Rutherford
(D) Niels Bohr
Answer: (B) James Chadwick (1932)
P2. Which isotope of hydrogen is present in heavy water?
(A) Protium
(B) Deuterium
(C) Tritium
(D) None
Answer: (B) Deuterium (D₂O) — used as a moderator in nuclear reactors.
P3. What is the maximum number of electrons that the M shell (n = 3) can hold?
(A) 8
(B) 18
(C) 32
(D) 2
Answer: (B) 18 — 2n² = 2 × 3² = 18.

📌 3. Periodic Table & Chemical Bonding (7 min read)

3.1 History of the Periodic Table

  • Döbereiner's Triads: groups of 3 elements each — Li, Na, K; Ca, Sr, Ba; Cl, Br, I (atomic mass of the middle one = average of the other two).
  • Newlands' Octaves: every 8th element is like the first (like musical notes) — true only up to Calcium.
  • Mendeleev (1869): arranged elements in order of atomic mass; 63 elements known at that time; left gaps and predicted new elements — eka-boron (Scandium), eka-aluminium (Gallium), eka-silicon (Germanium). "Father of Periodic Table".
  • Modern Periodic Law — Henry Moseley (1913): properties of elements are a periodic function of their atomic number.
  • Modern table: 18 groups (vertical) and 7 periods (horizontal); 118 elements today. Blocks: s, p, d, f. Lanthanides & Actinides (f-block) placed separately at the bottom.

3.2 Important Groups

GroupNameElements / Fact
1Alkali metalsLi, Na, K, Rb, Cs, Fr — very reactive, valency 1; Na/K are kept in kerosene
2Alkaline earth metalsBe, Mg, Ca, Sr, Ba, Ra — valency 2
3–12Transition elements (d-block)Fe, Cu, Zn, Mn, Cr, Ag, Au — coloured compounds, variable oxidation states, catalysts
17Halogens ("salt formers")F, Cl, Br, I, At — valency 1; F most reactive; Br is a liquid
18Noble / inert gasesHe, Ne, Ar, Kr, Xe, Rn — full outer shell, valency 0
  • Metalloids: B, Si, Ge, As, Sb, Te — properties of both metals and non-metals (Si, Ge = semiconductors).

3.3 Periodic Trends

PropertyAcross a period (left → right)Down a group (top → bottom)
Atomic sizeDecreasesIncreases
Metallic characterDecreasesIncreases
ElectronegativityIncreasesDecreases
Ionisation energyGenerally increasesDecreases
  • Electronegativity = the ability to pull the shared electrons of a bond towards itself. Fluorine is the most electronegative (Pauling scale 4.0) → the most non-metallic element. Order: F > O > N ≈ Cl.
  • Electron affinity = energy released on adding an electron. Highest for Chlorine (not Fluorine — because of its small size, F has electron-electron repulsion). The electron affinity of Nitrogen is almost zero — because its half-filled p-orbital (2p³) is extra stable. Noble gases also have almost zero/positive values.
  • Highest ionisation energy: Helium.

3.4 Chemical Bonding & Polarity

  • Ionic bond: transfer of electrons (metal → non-metal) — NaCl, MgO. High melting point, dissolve in water, conduct current when molten/dissolved.
  • Covalent bond: sharing of electrons — H₂, Cl₂, CH₄, H₂O. Single (H–H), double (O=O), triple (N≡N).
  • Hydrogen bond (H-bond): H + a highly electronegative atom (F, O, N) — because of it water has a high boiling point, ice floats on water, the two strands of DNA are held together, and the α-helix of proteins stays stable.
  • Dipole moment (μ = q × d, unit Debye): measure of polarity. In symmetrical molecules the dipoles cancel → μ = 0 (non-polar): CO₂ (linear), BeCl₂, BF₃ (trigonal planar), SO₃, CH₄, CCl₄, XeF₄ (square planar).
    Polar (μ ≠ 0): H₂O (bent), NH₃ (pyramidal), HCl, CHCl₃, SF₄ (see-saw shape, 1 lone pair).
  • Dipole moment of methyl halides: CH₃Cl > CH₃F > CH₃Br > CH₃I. (F is the most electronegative, but the C–F bond is short, so CH₃Cl is at the top.)
⚠️ Vyapam Alert (Exam Traps):
  • Most electronegative = Fluorine; highest electron affinity = Chlorine.
  • Mendeleev = atomic mass; Modern (Moseley) = atomic number.
  • BF₃, SO₃, XeF₄, CO₂, CCl₄ are non-polar (symmetry); SF₄, NH₃, H₂O are polar.
🎯 Official PYQs (MPESB SI Prelims 2025):
Q1. On the basis of electronegativity, which is the most non-metallic element?MPESB SI Prelims 2025 — 16 Jan 2026, Shift 2
(1) Fluorine
(2) Nitrogen
(3) Oxygen
(4) Sulphur
Correct answer: (1) Fluorine
Explanation: Fluorine has the highest electronegativity (4.0); the higher the electronegativity, the greater the non-metallic character.
Q2. The concept of atomic number was introduced by _______.MPESB SI Prelims 2025 — 18 Jan 2026, Shift 1
(1) Niels Bohr
(2) Ernest Rutherford
(3) Henry Moseley
(4) J. J. Thomson
Correct answer: (3) Henry Moseley
Explanation: Moseley showed through X-ray experiments that an element is identified by its atomic number (protons); the modern periodic law is based on this.
Q3. Which element in the second row of the periodic table has an electron affinity close to zero, mainly because of the stability of its half-filled p-orbital configuration?MPESB SI Prelims 2025 — 19 Jan 2026, Shift 2
(1) Carbon
(2) Nitrogen
(3) Oxygen
(4) Boron
Correct answer: (2) Nitrogen
Explanation: The configuration of N is 1s² 2s² 2p³ — one electron in each of the three p-orbitals (half-filled) = extra stable, so hardly any energy is released on taking a new electron.
Q4. Find the correct order of dipole moment.MPESB SI Prelims 2025 — 16 Jan 2026, Shift 1
(1) CH₃Br > CH₃Cl > CH₃I
(2) CH₃Cl > CH₃Br > CH₃I
(3) CH₃I > CH₃Br > CH₃Cl
(4) CH₃Cl > CH₃I > CH₃Br
Correct answer: (2) CH₃Cl > CH₃Br > CH₃I
Explanation: Going from Cl → Br → I, electronegativity decreases, so the dipole moment also decreases (approx: CH₃Cl 1.9 D, CH₃Br 1.8 D, CH₃I 1.6 D).
Q5. The most polar compound among the following is:MPESB SI Prelims 2025 — 21 Jan 2026, Shift 2
(1) BF₃
(2) SO₃
(3) SF₄
(4) XeF₄
Correct answer: (3) SF₄
Explanation: BF₃ and SO₃ are trigonal planar, XeF₄ is square planar — being symmetrical, μ = 0. SF₄ has a see-saw shape (one lone pair), which is asymmetrical, so it is polar.
✍️ Practice MCQs (self-made, not PYQs):
P1. How many groups and periods are there in the modern periodic table?
(A) 7 groups, 18 periods
(B) 18 groups, 7 periods
(C) 8 groups, 7 periods
(D) 16 groups, 9 periods
Answer: (B) 18 groups, 7 periods
P2. Which element did Mendeleev call 'eka-aluminium'?
(A) Scandium
(B) Germanium
(C) Gallium
(D) Boron
Answer: (C) Gallium — eka-silicon = germanium, eka-boron = scandium.
P3. Which of the following molecules has zero dipole moment?
(A) H₂O
(B) NH₃
(C) CO₂
(D) HCl
Answer: (C) CO₂ — linear (O=C=O), the two dipoles cancel.

📌 4. Chemical Reactions, Catalysts & Adsorption (7 min read)

4.1 Types of Reactions (NCERT Class 10)

TypeHow to identifyExample
CombinationA + B → ABCaO + H₂O → Ca(OH)₂ (slaked lime) + a lot of heat; C + O₂ → CO₂ (burning of coal)
DecompositionAB → A + BCaCO₃ → CaO + CO₂ (by heat — thermal); water → H₂ + O₂ (by electricity — electrolysis); 2AgBr → 2Ag + Br₂ (by sunlight — used in photography)
DisplacementA more reactive element displaces a less reactive oneFe + CuSO₄ → FeSO₄ + Cu (blue solution turns green, brown copper coating on the iron nail)
Double displacementExchange of ions; often a precipitateNa₂SO₄ + BaCl₂ → BaSO₄↓ (white) + 2NaCl
RedoxOxidation + Reduction togetherCuO + H₂ → Cu + H₂O
Exothermic / EndothermicHeat is released / absorbedExo: burning, respiration, CaO + water. Endo: photosynthesis, decomposition of CaCO₃
  • Oxidation: gain of oxygen / loss of hydrogen / loss of electrons. Reduction: loss of oxygen / gain of hydrogen / gain of electrons. A substance that gets reduced itself and oxidises another = oxidising agent.
  • Corrosion: Rust (Rust = Fe₂O₃·xH₂O) on iron — it needs both air (O₂) and moisture (water). Silver turns black (silver sulphide), copper turns green (basic copper carbonate). Prevention: paint, oil/grease, Galvanisation (= coating of zinc), alloys (stainless steel).
  • Rancidity: oily/ghee-rich food gets oxidised and smells bad. Prevention: antioxidants, airtight containers, nitrogen gas in chips packets, refrigerator.

4.2 Rate of Reaction & Catalyst

  • Rate increases with: concentration ↑, temperature ↑, surface area ↑ (powder reacts faster), Catalyst.
  • A Catalyst increases the rate but is not used up itself; it lowers the Activation energy (provides a new, easier path). Enzymes = biocatalysts.
  • Rate-determining step: in a multi-step reaction, the slowest step — i.e. the one with the highest activation energy. It decides the speed of the whole reaction.
Industrial processProductCatalyst
Haber processAmmonia NH₃ (N₂ + 3H₂)Iron (Fe)
Contact processSulphuric acid H₂SO₄V₂O₅ (Vanadium pentoxide)
Ostwald processNitric acid HNO₃Platinum (Pt)
Hydrogenation of oilsVanaspati ghee (oil → ghee)Nickel (Ni)

4.3 Advanced (12): Adsorption

  • Adsorption = particles of one substance collecting only on the surface of another (charcoal adsorbs gases — gas mask). Absorption = throughout the inside (water in a sponge).
PhysisorptionChemisorption
Weak van der Waals forcesA chemical bond is formed
Not specific (any gas)Specific — only for a particular adsorbate-adsorbent pair
ReversibleUsually irreversible
Low enthalpy (20–40 kJ/mol)High enthalpy (80–240 kJ/mol)
Multilayer (many layers)Unimolecular (one layer)
More at low temperatureIncreases with rise in temperature (up to a limit)
  • Assumptions of the Langmuir adsorption isotherm: (1) all adsorption sites on the surface are identical (equivalent/homogeneous); (2) only one layer (monolayer); (3) no interaction between adsorbed molecules.
⚠️ Vyapam Alert (Exam Traps):
  • Rusting needs both air + water; iron does not rust in only dry air or in boiled (oxygen-free) water.
  • A catalyst does not change the equilibrium/product of a reaction — only the speed (lower activation energy).
  • Rate-determining step = slowest step (not the fastest, not the last).
🎯 Official PYQs (MPESB SI Prelims 2025):
Q1. Which of the following statements is true for chemisorption but not for physisorption?MPESB SI Prelims 2025 — 17 Jan 2026, Shift 1
(1) Reversible in nature
(2) Multilayer formation
(3) Low enthalpy change
(4) Specific to the adsorbent and the adsorbate
Correct answer: (4) Specific
Explanation: In chemisorption a chemical bond is formed, so it happens only for a particular pair. Reversible, multilayer and low enthalpy — all three are properties of physisorption.
Q2. In a multi-step reaction, the rate-determining step is:MPESB SI Prelims 2025 — 18 Jan 2026, Shift 2
(1) The fastest step
(2) The last step
(3) The step with the highest activation energy
(4) The step with the lowest molecularity
Correct answer: (3)
Explanation: Highest activation energy = slowest step = the "bottleneck"; it decides the rate of the whole reaction.
Q3. The Langmuir adsorption isotherm is based on which assumption?MPESB SI Prelims 2025 — 20 Jan 2026, Shift 2
(1) The surface of the adsorbent is heterogeneous
(2) Adsorption is multilayer
(3) All adsorption sites are of the same nature
(4) There is interaction between adsorbed molecules
Correct answer: (3)
Explanation: Langmuir: homogeneous surface (all sites equivalent), monolayer, no interaction between adsorbed molecules. The other three options are the opposite of this.
✍️ Practice MCQs (self-made, not PYQs):
P1. What is coating iron with a layer of zinc called?
(A) Electrolysis
(B) Galvanisation
(C) Vulcanisation
(D) Calcination
Answer: (B) Galvanisation — to protect from rusting.
P2. The catalyst used in making ammonia by the Haber process is:
(A) Platinum
(B) Nickel
(C) Iron
(D) V₂O₅
Answer: (C) Iron
P3. Which gas is filled in chips packets to prevent oxidation (rancidity)?
(A) Oxygen
(B) Nitrogen
(C) Hydrogen
(D) Chlorine
Answer: (B) Nitrogen

📌 5. Acids, Bases & Salts (8 min read)

5.1 Basics

AcidBase
Sour taste; gives H⁺ (H₃O⁺) ions in waterBitter taste, soapy/slippery to touch; gives OH⁻ in water
Blue litmus → RedRed litmus → Blue
Strong: HCl, H₂SO₄, HNO₃ | Weak: CH₃COOH, carbonic acid, citric acidStrong: NaOH, KOH | Weak: NH₄OH. Bases that dissolve in water = Alkali
  • Neutralisation: Acid + Base → Salt + Water.
  • Acid + metal → salt + H₂ gas (a "pop" sound when a burning matchstick is brought near). Acid + carbonate/bicarbonate → salt + CO₂ + water (CO₂ turns lime water milky).
  • ⚠️ While diluting an acid, add acid to water, not water to acid (a lot of heat is released and it may splash).

5.2 Indicators

IndicatorIn acidIn base
Litmus (from lichen)RedBlue
PhenolphthaleinColourlessPink
Methyl orangeRedYellow
TurmericStays yellowReddish-brown (a turmeric stain turns red when soap is applied)
China rose (gudhal)Dark pink (magenta)Green
  • Olfactory (smell) indicators: onion, vanilla, clove — their smell disappears in a base.

5.3 pH Scale

  • pH = "potenz" (German: power) of H⁺; scale 0–14; given by S.P.L. Sørensen (1909). pH < 7 acidic, = 7 neutral (pure water), > 7 basic. When pH falls by 1, H⁺ concentration increases 10 times.
SubstancepH (approx.)Note
Gastric juice (HCl)~1.5–3.5Very acidic
Lemon juice~2.2–2.4Citric acid
Vinegar~3Acetic acid
Milk~6.5Slightly acidic; pH falls further when it turns into curd
Pure water7Neutral
Human blood7.35–7.45 (~7.4)Slightly basic
Milk of magnesia (Mg(OH)₂)~10Antacid
  • Teeth: when the pH of the mouth falls below 5.5, enamel (calcium hydroxyapatite — the hardest substance in the body) starts dissolving → tooth decay. Toothpaste is basic.
  • Acid rain: rain with pH less than 5.6 (due to SO₂, NOₓ).
  • Acidity in the stomach: antacid — milk of magnesia Mg(OH)₂ or baking soda.
  • Soil: quicklime (CaO) / slaked lime (Ca(OH)₂) / chalk is added to very acidic soil; organic matter (manure) to very basic soil.
  • Insect sting: the sting of an ant/nettle contains methanoic (formic) acid → relief with a mild base like baking soda.

5.4 Natural Acids (must memorise)

SourceAcid
VinegarAcetic / ethanoic acid (CH₃COOH)
Lemon, orange (Citrus)Citric acid
Tamarind, grapesTartaric acid
Tomato, spinachOxalic acid
Curd / sour milkLactic acid
Ant sting, NettleMethanoic / formic acid (HCOOH)
AppleMalic acid
AmlaAscorbic acid (Vitamin C)
StomachHydrochloric acid (HCl)
Soda water / cold drinksCarbonic acid (H₂CO₃)

5.5 Everyday Salts (NCERT Class 10)

Common nameChemical name & formulaHow it is made / Uses
Common saltSodium chloride — NaClSea water / rock salt (sendha namak). Used to make NaOH, baking soda, washing soda, bleaching powder
Caustic sodaSodium hydroxide — NaOHChlor-alkali process: electrolysis of brine (NaCl solution) → NaOH + Cl₂ (anode) + H₂ (cathode)
Bleaching powderCalcium oxychloride — CaOCl₂Cl₂ on dry slaked lime Ca(OH)₂. Disinfecting drinking water, bleaching cloth (cotton/linen)
Baking sodaSodium hydrogen carbonate (bicarbonate) — NaHCO₃Gives CO₂ on heating → cake/dhokla rises; antacid; soda-acid fire extinguisher. Baking powder = baking soda + tartaric acid
Washing sodaSodium carbonate decahydrate — Na₂CO₃·10H₂OGlass, soap, paper industries; cleaning; removing permanent hardness of water
Plaster of Paris (POP)Calcium sulphate hemihydrate — CaSO₄·½H₂OBy heating Gypsum (CaSO₄·2H₂O) at 373 K. On adding water it becomes hard gypsum again. Plaster for broken bones, toys, statues. Keep away from moisture
Blue vitriol (neela thotha)Copper sulphate pentahydrate — CuSO₄·5H₂OBlue; on heating, the water of crystallisation evaporates and it turns white (anhydrous)
⚠️ Vyapam Alert (Exam Traps):
  • Baking soda = NaHCO₃ (bi-carbonate); Washing soda = Na₂CO₃·10H₂O (10 water molecules); do not mix them up.
  • POP has ½ H₂O, Gypsum has 2 H₂O.
  • Blood pH ~7.4 = slightly basic (not acidic). Pure water = 7.
  • Phenolphthalein is colourless in acid, pink in base.
  • Tomato = oxalic; Tamarind = tartaric; Curd = lactic; Ant sting = formic (methanoic).
✍️ Practice MCQs (self-made, not PYQs — no direct question came from this topic in the 2025 paper, but this is basic GK):
P1. What is the approximate pH value of human blood?
(A) 6.4
(B) 7.0
(C) 7.4
(D) 8.2
Answer: (C) 7.4 — 7.35 to 7.45, slightly basic.
P2. What is the chemical formula of baking soda?
(A) Na₂CO₃
(B) NaHCO₃
(C) CaCO₃
(D) NaOH
Answer: (B) NaHCO₃ (Sodium hydrogen carbonate).
P3. Which acid is found in an ant sting?
(A) Acetic acid
(B) Tartaric acid
(C) Methanoic (formic) acid
(D) Oxalic acid
Answer: (C) Methanoic (Formic) acid
P4. At what temperature is gypsum heated to make Plaster of Paris?
(A) 273 K
(B) 373 K
(C) 573 K
(D) 1000 K
Answer: (B) 373 K (100°C)
P5. What colour does phenolphthalein give in a basic solution?
(A) Red
(B) Pink
(C) Yellow
(D) Colourless
Answer: (B) Pink

📌 6. Metals, Non-metals, Ores & Alloys (8 min read)

6.1 Metals vs Non-metals (Properties)

MetalsNon-metals
Shiny (lustre), hard, malleable — can be beaten into sheets, ductile — can be drawn into wires, sonorousUsually brittle, no lustre, not sonorous
Good conductors of heat and electricity — Silver (Ag) is the best, then CopperPoor conductors (except graphite)
Oxides are basic (Na₂O, MgO)Oxides are acidic (CO₂, SO₂) or neutral (CO, H₂O)
Form positive ions by giving electronsForm negative ions by taking electrons

6.2 Exceptions (asked most often)

  • Mercury, Hg — a liquid metal at room temperature. Bromine (Br) — a liquid non-metal.
  • Gallium, Caesium — melting point so low that they melt on the palm.
  • Sodium, Potassium — so soft that they can be cut with a knife; they catch fire in air, so they are kept in kerosene. White phosphorus burns in air → kept in water.
  • Iodine — a non-metal, yet shiny. Graphite — a non-metal, yet a conductor of electricity. Diamond — the hardest natural substance, very high melting point.
  • Gold, Silver — the most malleable/ductile (1 g of gold gives a wire ~2 km long). Lead, Mercury — poor conductors of heat.
  • Tungsten — the highest melting point among metals → bulb filament. Lithium — the lightest metal. Osmium — the densest metal.
  • In the Earth's crust: the most abundant element is Oxygen, then Silicon; the most abundant metal is Aluminium, then Iron.
  • Aluminium oxide (Al₂O₃), Zinc oxide (ZnO) = amphoteric — react with both acids and bases.

6.3 Reactivity Series

K > Na > Ca > Mg > Al > Zn > Fe > Pb > [H] > Cu > Hg > Ag > Au
Trick: "Kaise NahaCar Mgan Ali Znak Feke Pbar Hota Cuchh Hg Ag Au" (a Roman Hindi mnemonic; the bold letters give the symbols in order: K, Na, Ca, Mg, Al, Zn, Fe, Pb, H, Cu, Hg, Ag, Au).
• Metals above H release H₂ from dilute acids; Cu, Hg, Ag, Au do not.
• Aqua regia = 3 parts conc. HCl + 1 part conc. HNO₃ — dissolves even gold (Au) and platinum.

6.4 Metallurgy (short)

  • Mineral = a compound found in nature; Ore = a mineral from which the metal can be extracted profitably. Useless soil/sand = gangue.
  • Roasting: heating a sulphide ore in excess air. Calcination: heating a carbonate ore in limited/no air.
  • Low reactivity (Hg, Cu) — by heating alone; medium (Zn, Fe, Pb) — reduction with carbon; very reactive (Na, Mg, Ca, Al) — by electrolysis.
  • Thermite reaction: Fe₂O₃ + 2Al → 2Fe + Al₂O₃ + a lot of heat → joining railway tracks.
  • Electrolytic refining: impure metal = anode, thin strip of pure metal = cathode.

6.5 Important Ores

MetalOre & formula
Aluminium (Al)Bauxite Al₂O₃·2H₂O; Cryolite Na₃AlF₆
Iron (Fe)Haematite Fe₂O₃; Magnetite Fe₃O₄ (highest iron %, magnetic); Siderite FeCO₃
Copper (Cu)Copper pyrite CuFeS₂; Cuprite Cu₂O; Malachite
Zinc (Zn)Zinc blende ZnS; Calamine ZnCO₃
Mercury (Hg)Cinnabar HgS
Lead (Pb)Galena PbS
Tin (Sn)Cassiterite SnO₂
Silver (Ag)Argentite Ag₂S
Magnesium (Mg)Magnesite MgCO₃; Dolomite CaCO₃·MgCO₃; Carnallite KCl·MgCl₂·6H₂O
Sodium (Na)Rock salt NaCl
Uranium (U)Pitchblende

📍 MP link: Malajkhand (Balaghat) — the country's largest open-cast copper mine; Panna — diamond mine (Majhgawan).

6.6 Alloys

AlloyComponentsUses
BrassCu + ZnUtensils, statues, fittings
BronzeCu + Sn (tin)Medals, statues, bells
German silverCu + Zn + Ni (no silver!)Utensils, decoration
Gun metalCu + Sn + ZnGuns, gears
Stainless steelFe + Cr + Ni (+ C)Does not rust — utensils, surgical instruments
SolderPb + SnLow melting point — joining electric wires
DuraluminAl + Cu + Mg + MnLight and strong — aircraft
MagnaliumAl + MgScientific instruments, light parts
NichromeNi + Cr (+ Fe)Heater/iron coils (high resistance)
AmalgamHg + any metalFilling teeth
  • The electrical conductivity and melting point of an alloy are lower than those of the pure metal.
  • 24 carat = pure gold (soft). 22 carat = 22 parts gold + 2 parts copper/silver (~91.6%).

6.7 Advanced (12): d-block — KMnO₄

  • Potassium permanganate (KMnO₄, "lal dawa") — deep purple. The oxidation state of Mn is +7 (d⁰), so a d-d transition is not possible; the colour comes from charge transfer (oxygen → manganese).
  • In the lab, peroxodisulphate (S₂O₈²⁻) is used to oxidise Mn²⁺ to MnO₄⁻.
  • KMnO₄: strong oxidising agent, disinfectant for water/wells. K₂Cr₂O₇ — orange.
  • Transition metals: coloured compounds, variable oxidation states, catalysts (Fe, Ni, Pt, V₂O₅).
⚠️ Vyapam Alert (Exam Traps):
  • Brass = Cu + Zn; Bronze = Cu + Sn (the most common confusion).
  • German silver contains no silver.
  • Na/K = kerosene; white phosphorus = water.
  • Cinnabar = Hg; Galena = Pb; Bauxite = Al; Haematite = Fe.
  • Best conductor = Silver (not Copper — copper is used in wires because it is cheaper).
🎯 Official PYQs (MPESB SI Prelims 2025):
Q1. In the laboratory, which of the following special oxidising agents is used to oxidise Mn²⁺ to MnO₄⁻?MPESB SI Prelims 2025 — 18 Jan 2026, Shift 2
(1) Hydrogen peroxide
(2) Peroxodisulphate
(3) Potassium nitrate
(4) Nitric acid
Correct answer: (2) Peroxodisulphate
Explanation: NCERT (class 12, d-block): 2Mn²⁺ + 5S₂O₈²⁻ + 8H₂O → 2MnO₄⁻ + 10SO₄²⁻ + 16H⁺. Peroxodisulphate is a very powerful oxidising agent.
Q2. The deep purple colour of potassium permanganate is caused by:MPESB SI Prelims 2025 — 19 Jan 2026, Shift 2
(1) d–d electronic transitions
(2) Charge transfer from oxygen to manganese
(3) Ligand field splitting in a d⁷ system
(4) π-back bonding in Mn–O bonds
Correct answer: (2) Charge transfer (O → Mn)
Explanation: In MnO₄⁻, Mn is +7 (d⁰ — no d-electrons), so a d-d transition cannot happen. Electrons of oxygen absorb light while moving towards Mn (ligand-to-metal charge transfer) → purple colour.
✍️ Practice MCQs (self-made, not PYQs):
P1. Brass is an alloy of which metals?
(A) Copper + Tin
(B) Copper + Zinc
(C) Iron + Chromium
(D) Lead + Tin
Answer: (B) Cu + Zn
P2. Sodium metal is kept immersed in:
(A) Water
(B) Alcohol
(C) Kerosene
(D) Acid
Answer: (C) Kerosene
P3. Cinnabar is an ore of which metal?
(A) Lead
(B) Mercury
(C) Zinc
(D) Tin
Answer: (B) Mercury (HgS)
P4. The ratio of HCl and HNO₃ in aqua regia is:
(A) 1 : 3
(B) 3 : 1
(C) 1 : 1
(D) 2 : 1
Answer: (B) 3 : 1 (3 HCl : 1 HNO₃).

📌 7. Carbon Compounds, Soaps & Detergents (8 min read)

7.1 Properties of Carbon & Allotropes

  • Carbon has valency 4 (tetravalency); its property of forming long chains with itself = Catenation → hence lakhs of carbon compounds.
  • Carbon forms covalent bonds (giving/taking 4 electrons is difficult).
AllotropeStructureProperties / Uses
DiamondEach C bonded to 4 C — rigid 3D networkHardest natural substance; non-conductor of electricity; cutting glass, jewellery
GraphiteEach C bonded to 3 C — hexagonal layersSlippery, conductor of electricity; pencil "lead", lubricant, electrode
Fullerene (C₆₀)Shaped like a footballNamed after architect Buckminster Fuller

Amorphous forms: coal, charcoal (wood charcoal), coke, lamp black.

7.2 Hydrocarbons

TypeBondGeneral formulaExamples
Alkane — saturatedOnly single C–CCₙH₂ₙ₊₂Methane CH₄ (marsh gas, CNG/biogas), Ethane C₂H₆, Propane C₃H₈, Butane C₄H₁₀ (LPG)
Alkene — unsaturatedDouble C=CCₙH₂ₙEthene C₂H₄ (ripening fruit, monomer of polythene)
Alkyne — unsaturatedTriple C≡CCₙH₂ₙ₋₂Ethyne / Acetylene C₂H₂ — welding with oxygen
  • Saturated hydrocarbons burn with a blue (clean) flame; unsaturated ones with a yellow, smoky flame.
  • Benzene C₆H₆ — aromatic ring. Positions of two substituents: ortho = 1,2; meta = 1,3; para = 1,4. E.g. para-dichlorobenzene = 1,4-dichlorobenzene.

7.3 Functional Groups

GroupSuffixExample / Fact
Alcohol –OH-olEthanol C₂H₅OH (liquor, sanitizer, medicines). Denatured alcohol = ethanol + methanol (+ colour) so that it is unfit to drink. Drinking methanol causes blindness/death
Aldehyde –CHO-alMethanal (formaldehyde); formalin (~40% solution) — preserving biological specimens
Ketone >C=O-oneAcetone (propanone) — nail polish remover; progesterone (hormone) has a ketone group
Carboxylic acid –COOH-oic acidEthanoic acid CH₃COOH; vinegar = 5–8% acetic acid; pure = glacial acetic acid (freezes in cold weather)
Ester –COOR-oateSweet/fruity smell — perfumes, flavours
Amine –NH₂-amineMethylamine, aniline
  • Esterification: acid + alcohol → ester + water (acid catalyst).
  • Saponification: ester (oil/fat) + NaOH → soap + glycerol/alcohol.
  • Advanced (12): Gabriel phthalimide synthesis gives only primary aliphatic amines (ethylamine, n-propylamine, benzylamine). Aromatic amines (aniline) and tert-butylamine cannot be made (aryl halides / tertiary halides do not undergo SN2 reaction; a tertiary halide undergoes elimination).

7.4 Soaps & Detergents

  • Soap = sodium/potassium salts of long-chain fatty acids (Na → hard soap, K → soft/liquid soap).
  • Detergent = long-chain sulphonate or ammonium salts. They work even in hard water; soap forms scum (precipitate) with hard water (Ca²⁺, Mg²⁺).
  • Soap molecule: one end is ionic, hydrophilic (–COO⁻Na⁺) → towards water; the other is a long hydrocarbon tail, hydrophobic → towards oil/dirt.
  • Micelle: in water, soap molecules form a sphere — tails inside (hold the oil/dirt), ionic ends outside towards the water. The dirt gets trapped in the middle of the micelle and is washed away with the water.
  • Advanced (12): A micelle forms only above a certain concentration (CMC — Critical Micelle Concentration) and above a certain temperature (Krafft temperature, Tk). That is why soap cleans less well in very cold water. Needed for a micelle: enough concentration, a non-polar tail, a polar solvent (water) — low temperature is not needed.
⚠️ Vyapam Alert (Exam Traps):
  • In a micelle, the part facing water = ionic (carboxylate) head; the tail is inside.
  • Soap works less in cold water = below the Krafft temperature (not cloud point / freezing point).
  • Graphite = conductor; Diamond = non-conductor (both are carbon).
  • Para = 1,4; Ortho = 1,2; Meta = 1,3.
🎯 Official PYQs (MPESB SI Prelims 2025):
Q1. In a micelle formed by soap in water, which part of the soap molecule faces the water?MPESB SI Prelims 2025 — 17 Jan 2026, Shift 2
(1) Hydrocarbon tail
(2) Ionic (carboxylate) head
(3) Non-polar end
(4) Both ends equally
Correct answer: (2) Ionic (carboxylate) head
Explanation: The ionic end is hydrophilic, so it faces the water; the hydrocarbon tail is hydrophobic, so it stays inside towards the oil.
Q2. Which of the following conditions is not necessary for the formation of micelles by soap in water?MPESB SI Prelims 2025 — 18 Jan 2026, Shift 2
(1) Sufficiently high concentration
(2) Low temperature
(3) Presence of a non-polar group
(4) A polar solvent like water
Correct answer: (2) Low temperature
Explanation: Micelles form above the Krafft temperature — so a low temperature is actually a hindrance. Concentration above the CMC, a non-polar tail and a polar solvent are necessary.
Q3. The cleansing action of soap decreases in cold water when the temperature falls below which specific limit?MPESB SI Prelims 2025 — 19 Jan 2026, Shift 2
(1) Cloud point
(2) Critical micelle concentration
(3) Freezing point
(4) Krafft temperature
Correct answer: (4) Krafft temperature
Explanation: Below the Krafft temperature micelles do not form, so cleaning is reduced. CMC is a concentration, not a temperature.
Q4. What is the IUPAC name of a benzene ring substituted by two chlorine atoms at the para position?MPESB SI Prelims 2025 — 20 Jan 2026, Shift 1
(1) 1,2-Dichlorobenzene
(2) 1,3-Dichlorobenzene
(3) 1,4-Dichlorobenzene
(4) Chlorobenzene
Correct answer: (3) 1,4-Dichlorobenzene
Explanation: Para = opposite each other (1 and 4). Ortho = 1,2; meta = 1,3.
Q5. Which of the following amines cannot be prepared by Gabriel phthalimide synthesis?MPESB SI Prelims 2025 — 19 Jan 2026, Shift 1
(1) Benzylamine
(2) tert-Butylamine
(3) n-Propylamine
(4) Ethylamine
Correct answer: (2) tert-Butylamine
Explanation: In Gabriel synthesis, the phthalimide ion makes an SN2 attack on an alkyl halide. A tert-butyl halide does not undergo SN2 (elimination happens instead), so tert-butylamine is not formed. The other three are made from primary halides.
Q6. Which of the following functional groups is present in progesterone?MPESB SI Prelims 2025 — 21 Jan 2026, Shift 2
(1) Ester
(2) Ketone
(3) Aldehyde
(4) Ether
Correct answer: (2) Ketone
Explanation: Progesterone is a steroid hormone that has two >C=O (ketone) groups.
✍️ Practice MCQs (self-made, not PYQs):
P1. Which allotrope of carbon is a good conductor of electricity?
(A) Diamond
(B) Graphite
(C) Fullerene
(D) None
Answer: (B) Graphite — each C has one free electron.
P2. About what percentage of acetic acid is present in vinegar?
(A) 1–2%
(B) 5–8%
(C) 20–25%
(D) 50%
Answer: (B) 5–8%
P3. Which gas is burnt with oxygen in welding?
(A) Methane
(B) Ethene
(C) Ethyne (Acetylene)
(D) Butane
Answer: (C) Ethyne (Acetylene)

📌 8. Common Chemicals, Fuels & Fertilizers (8 min read)

8.1 Common Names & Formulas

Common nameChemical nameFormulaUses / Fact
QuicklimeCalcium oxideCaOReleases a lot of heat with water
Slaked limeCalcium hydroxideCa(OH)₂Whitewash; its solution = lime water
Limestone / chalk / marbleCalcium carbonateCaCO₃Cement; acid rain damages the marble of the Taj Mahal
GypsumCalcium sulphate dihydrateCaSO₄·2H₂OMaking POP; in cement (to slow down setting)
Potash alum (phitkari)Potassium aluminium sulphateK₂SO₄·Al₂(SO₄)₃·24H₂OPurifying dirty water (settles the mud), after shaving
Green vitriolFerrous sulphateFeSO₄·7H₂OGreen
White vitriolZinc sulphateZnSO₄·7H₂O
Epsom saltMagnesium sulphateMgSO₄·7H₂OLaxative
Glauber's saltSodium sulphateNa₂SO₄·10H₂O
Caustic potashPotassium hydroxideKOHSoft soap
Sal ammoniac (nausadar)Ammonium chlorideNH₄ClDry cell; sublimes
Saltpetre (shora)Potassium nitrateKNO₃Gunpowder, crackers. Chile saltpetre = NaNO₃
Lunar causticSilver nitrateAgNO₃Election ink (indelible ink)
Silver bromide / iodide—AgBr / AgIAgBr — photography; AgI — artificial rain (cloud seeding)
HypoSodium thiosulphateNa₂S₂O₃·5H₂OPhotography (fixing)
Borax (suhaga)Sodium tetraborateNa₂B₄O₇·10H₂OGlass, goldsmith's work
Muriatic acidHydrochloric acidHClAlso produced in the stomach
Oil of vitriolSulphuric acidH₂SO₄"King of chemicals"; car battery
Dry iceSolid carbon dioxideCO₂ (s)Refrigerant; sublimes
Heavy waterDeuterium oxideD₂OModerator in nuclear reactors
Laughing gasNitrous oxideN₂OIn anaesthesia
Marsh gasMethaneCH₄Main component of CNG, biogas
CalomelMercurous chlorideHg₂Cl₂
Sindoor (Red lead)Lead tetroxidePb₃O₄
CarborundumSilicon carbideSiCAbrasive (for grinding)
Sand / quartzSilicon dioxideSiO₂Making glass
Calcium carbide—CaC₂Artificial ripening of fruit (releases acetylene) — banned
Zinc phosphide—Zn₃P₂Rat poison
  • 📍 MP link — Bhopal Gas Tragedy (2–3 Dec 1984): leak of methyl isocyanate (MIC) gas from the Union Carbide factory — one of the world's biggest industrial disasters.
  • Tear gas — used by police for crowd control: today mainly CS and CN (chloroacetophenone) gas.
  • Monosodium glutamate (MSG / Ajinomoto) — flavour enhancer; Sodium benzoate — food preservative.

8.2 Fuels

  • Calorific value = heat released when 1 kg of fuel burns completely (kJ/kg). A good fuel: high calorific value, cheap, easily available, little smoke/pollution, moderate ignition temperature.
FuelCalorific value (kJ/kg) — NCERT Class 8
Cow dung cake6,000–8,000 (lowest)
Wood17,000–22,000
Coal25,000–33,000
Biogas35,000–40,000
Petrol / Kerosene / Diesel45,000
Methane / CNG50,000
LPG55,000
Hydrogen1,50,000 (highest) — but difficult to store/transport and explosive
  • LPG — mainly butane (+ propane); it is odourless, so ethyl mercaptan is added to detect leaks. CNG — mainly methane. Biogas — methane (NCERT: up to ~75%) + CO₂; in a gobar gas plant, made by anaerobic (without oxygen) bacteria.
  • Water gas = CO + H₂; Producer gas = CO + N₂; Coal gas = H₂ + CH₄ + CO.
  • Types of coal (in increasing order of carbon %): Peat < Lignite < Bituminous < Anthracite (best). The slow conversion of dead vegetation into coal over millions of years = carbonisation (NCERT Class 8).
  • From coal: coke (almost pure carbon — used in making steel), coal tar (naphthalene balls, dyes, explosives, perfumes), coal gas.
  • Petroleum ("black gold") → fractional distillation in a refinery → LPG, petrol, kerosene, diesel, lubricating oil, paraffin wax, bitumen (roads).
  • Octane number — ability of petrol to prevent "knocking" (higher = better). For diesel, cetane number.
  • Incomplete burning → CO (carbon monoxide) — poisonous, colourless and odourless; it binds with haemoglobin and stops it from carrying oxygen (an angithi/coal stove in a closed room is dangerous).
  • Zones of a flame (NCERT 8): outermost — blue, hottest, complete combustion (used by goldsmiths); middle — yellow, luminous, partial combustion; innermost — black, unburnt wax vapour.
  • Fire fighting: no water on electrical or oil fires — a CO₂ extinguisher is best (cuts off the oxygen supply and does not damage equipment).

8.3 Fertilizers

  • Main plant nutrients: N, P, K (nitrogen, phosphorus, potassium).
  • Urea — CO(NH₂)₂ — highest nitrogen (~46%). Made from ammonia (Haber process) + CO₂.
  • DAP (Diammonium phosphate) — N + P; SSP (Single superphosphate) — P; MOP (Muriate of potash = KCl) — K; ammonium sulphate, ammonium nitrate, CAN.
  • Biofertilizers: Rhizobium (fixes N₂ in the root nodules of pulses / legumes), Azotobacter, Anabaena / Nostoc (blue-green algae — paddy fields), Mycorrhiza (phosphorus).
  • Organic manure improves soil structure; excessive use of chemical fertilizers pollutes soil and water.
⚠️ Vyapam Alert (Exam Traps):
  • Highest calorific value = Hydrogen; LPG > CNG > Petrol.
  • LPG = butane (also propane); CNG = methane; Biogas = methane.
  • Best coal = Anthracite; lowest = Peat.
  • Election ink = Silver nitrate; artificial rain = Silver iodide.
  • Bhopal gas = Methyl isocyanate (MIC).
✍️ Practice MCQs (self-made, not PYQs):
P1. Which gas leaked in the Bhopal Gas Tragedy (1984)?
(A) Phosgene
(B) Methyl isocyanate
(C) Chlorine
(D) Ammonia
Answer: (B) Methyl isocyanate (MIC)
P2. Which fuel has the highest calorific value?
(A) LPG
(B) CNG
(C) Hydrogen
(D) Petrol
Answer: (C) Hydrogen (~1,50,000 kJ/kg).
P3. Which chemical is present in the ink put on the finger during elections?
(A) Silver iodide
(B) Silver nitrate
(C) Potassium permanganate
(D) Copper sulphate
Answer: (B) Silver nitrate (AgNO₃)
P4. The main component of LPG is:
(A) Methane
(B) Ethane
(C) Butane
(D) Hydrogen
Answer: (C) Butane
P5. Which fertilizer has the highest nitrogen content?
(A) Ammonium sulphate
(B) Urea
(C) Superphosphate
(D) Potash
Answer: (B) Urea (~46% N)

📌 9. Polymers & Plastics (7 min read) — 6 questions in 2025!

9.1 Basics

  • Polymer = a large molecule formed by repeated joining of small units (monomers). E.g. ethene → polythene.
  • Natural: starch, cellulose (cotton/wood), protein, DNA, natural rubber (polyisoprene), silk (protein fibroin), wool (protein keratin).
  • Semi-synthetic: Rayon ("artificial silk") — from wood pulp (cellulose); vulcanised rubber.
  • Synthetic: nylon, polyester, PVC, polythene, Teflon, Bakelite, acrylic.

9.2 Thermoplastic vs Thermosetting

ThermoplasticThermosetting
Softens on heating, can be reshaped again and againOnce moulded, does not soften on heating
Polythene, PVC, polystyrene, nylon, PETBakelite (electric switches, utensil handles — poor conductor of electricity/heat), Melamine (crockery, fire-resistant fabrics)

9.3 Important Polymers & Uses

PolymerMonomer / NoteUses
PolytheneEtheneBags, bottles
PVCVinyl chloridePipes, wire insulation, raincoats
Teflon (PTFE)Tetrafluoroethene (CF₂=CF₂)Non-stick cookware; strong C–F bond + a fluorine "shield" all around the carbon chain → protection from chemical attack, heat resistant
NylonNylon-6,6: hexamethylenediamine + adipic acid; Nylon-6: caprolactam (made from cyclohexanone)First fully synthetic fibre (NCERT: 1931); ropes, parachutes, toothbrushes, socks
Polyester / Terylene (PET)Ethylene glycol + terephthalic acidClothes (terrycot), PET bottles
Acrylic (PAN)AcrylonitrileWool-like (sweaters, blankets) — cheap
Polycarbonate—Transparency + very high impact resistance → bulletproof sheets, helmet visors, safety glasses (does not break like ordinary glass)
BakelitePhenol + formaldehydeSwitches, handles (thermosetting)
Natural rubberIsoprene (cis-polyisoprene)Vulcanisation — heating with sulphur (Charles Goodyear) → strong, elastic
Synthetic rubberNeoprene (chloroprene), Buna-S (butadiene + styrene), Buna-NTyres, conveyor belts, hoses
  • Elastomers: rubber-like polymers — they stretch when pulled and return to their original shape when released (weak van der Waals forces). Natural rubber, neoprene, Buna-S.
  • Fibres: strong intermolecular forces (H-bonds) → high tensile strength (nylon, polyester, silk).
  • Wool and silk = fibrous proteins — long thread-like structure, strong intermolecular forces, insoluble in water → can form fibres. Albumin (egg white) = globular protein — spherical, soluble in water → does not form fibres.

9.4 Biodegradable Polymers & the Plastic Problem

  • Most plastics are non-biodegradable — do not decompose for years; release poisonous gases when burnt. 5R: Reduce, Reuse, Recycle, Recover, Refuse.
  • Biodegradable polymers: PHBV, Nylon-2-Nylon-6, starch-based plastics.
  • Limitation of starch plastic: starch absorbs water/moisture and its mechanical properties (mechanical strength) are weak.
⚠️ Vyapam Alert (Exam Traps):
  • Non-stick = Teflon; switch/handle = Bakelite; artificial silk = Rayon; substitute for wool = Acrylic.
  • Strengthening rubber with sulphur = Vulcanisation (Galvanisation = zinc coating — do not confuse).
  • How to identify an elastomer = it stretches and comes back.
🎯 Official PYQs (MPESB SI Prelims 2025):
Q1. Why is the use of starch as a biodegradable plastic limited?MPESB SI Prelims 2025 — 16 Jan 2026, Shift 2
(1) Its molecular weight is very high
(2) It is very expensive to produce commercially
(3) It absorbs moisture and has poor mechanical properties
(4) It cannot be processed by conventional methods
Correct answer: (3)
Explanation: Starch is hydrophilic — it absorbs moisture and becomes soft/weak; its strength is low. Starch is cheap, not expensive.
Q2. Choose the most suitable reason why Teflon (PTFE) has excellent chemical resistance.MPESB SI Prelims 2025 — 17 Jan 2026, Shift 2
(1) Its high molecular weight and crystallinity
(2) The strength of the C–F bond and the protective fluorine sheath around the carbon backbone
(3) Its linear structure with no branching
(4) Absence of any reactive functional group
Correct answer: (2)
Explanation: The C–F bond is very strong and the fluorine atoms fully cover the carbon chain, so no reagent can even reach the chain.
Q3. Why are proteins like wool and silk used as fibres, while other proteins like albumin are not?MPESB SI Prelims 2025 — 20 Jan 2026, Shift 1
(1) Wool and silk have a higher molecular weight
(2) Wool and silk have fibrous structures with strong intermolecular forces
(3) Albumin dissolves in water while wool and silk do not
(4) Wool and silk contain aromatic amino acids
Correct answer: (2)
Explanation: The chains of fibrous proteins (keratin, fibroin) are long and held together by strong forces like H-bonds → threads (fibres). Albumin is a globular protein — a folded, spherical structure. Option (3) is a fact, but the basic reason for "why fibre" is the structure (option 2).
Q4. Why is polycarbonate preferred over ordinary glass for safety applications?MPESB SI Prelims 2025 — 20 Jan 2026, Shift 2
(1) It has better optical clarity than glass
(2) It combines high impact resistance with transparency
(3) It is lighter in weight than glass
(4) It has better thermal stability than glass
Correct answer: (2)
Explanation: For safety, the material must be transparent and must not break when hit by a blow/bullet — polycarbonate gives both (bulletproof sheets, visors).
Q5. Which ketone is used for the manufacture of nylon?MPESB SI Prelims 2025 — 21 Jan 2026, Shift 1
(1) Cyclohexanone
(2) Cyclopentanone
(3) Acetophenone
(4) Benzophenone
Correct answer: (1) Cyclohexanone
Explanation: Cyclohexanone → (oxime) → caprolactam → Nylon-6. Cyclohexanone also gives adipic acid, which is a monomer of Nylon-6,6.
Q6. The classification of polymers as elastomers is based on which criterion?MPESB SI Prelims 2025 — 21 Jan 2026, Shift 1
(1) Their ability to stretch and return to their original shape
(2) Their high tensile strength
(3) Their resistance to chemical attack
(4) Their transparency and optical properties
Correct answer: (1)
Explanation: Elastomer = elastic polymer. High tensile strength is the identifying feature of fibres.
✍️ Practice MCQs (self-made, not PYQs):
P1. Non-stick cookware is coated with which polymer?
(A) PVC
(B) Teflon
(C) Bakelite
(D) Nylon
Answer: (B) Teflon
P2. Vulcanisation of rubber is done with which element?
(A) Carbon
(B) Sulphur
(C) Phosphorus
(D) Zinc
Answer: (B) Sulphur
P3. What is called 'artificial silk'?
(A) Nylon
(B) Rayon
(C) Acrylic
(D) Polyester
Answer: (B) Rayon — from wood pulp (cellulose).

📌 10. Biomolecules & Chemistry in Daily Life (7 min read)

10.1 Carbohydrates

TypeExamplesFact
Monosaccharide (Mono)Glucose (grape sugar), Fructose (fruit sugar — the sweetest natural sugar), GalactoseAll are reducing sugars
Disaccharide (Di)Sucrose (table sugar) = glucose + fructose; Lactose (milk) = glucose + galactose; Maltose = glucose + glucoseSucrose = non-reducing; lactose, maltose = reducing
Polysaccharide (Poly)Starch (storage in plants), Cellulose (cell wall — humans cannot digest it), Glycogen ("animal starch" — in liver and muscles)Not sweet
  • Reducing sugar — reduces Fehling's solution (blue → red Cu₂O precipitate) and Tollens' reagent (silver mirror); for this it needs a free aldehyde/ketone (anomeric carbon).
  • Two monosaccharides join by a glycosidic linkage. In sucrose, C1 of glucose and C2 of fructose — both carbonyl carbons get locked in the bond (acetal/ketal linkage), so sucrose is not reducing.

10.2 Proteins, Enzymes & Nucleic Acids

  • Protein = a chain of amino acids joined by peptide bonds. About ~20 amino acids in all.
    • Essential amino acids — the body cannot make them itself; they must come from food (valine, leucine, lysine, tryptophan, phenylalanine...). Non-essential — the body can make them. (Basis of classification = the body's ability to synthesise them.)
    • Fibrous proteins (keratin — hair/wool/nails, collagen, fibroin — silk, myosin) — insoluble in water. Globular (albumin, insulin, haemoglobin, enzymes) — soluble.
    • Structure: primary (sequence), secondary (α-helix, β-pleated sheet — stabilised by H-bonds), tertiary, quaternary. Denaturation: structure is destroyed by heat/acid — boiling an egg, curdling of milk.
  • Enzymes = biocatalysts (mostly proteins); they lower activation energy; highly specific. According to NCERT, 6 classes — based on the type of reaction they catalyse: oxidoreductases, transferases, hydrolases, lyases, isomerases, ligases.
    Examples: zymase (sugar → ethanol, yeast), invertase (sucrose → glucose + fructose), diastase (starch → maltose), pepsin (protein).
  • Nucleic acids: DNA (deoxyribose; A, T, G, C) and RNA (ribose; A, U, G, C) — details on the Biology page.

10.3 Medicines & Everyday Chemicals

ClassActionExamples
AnalgesicReduces painAspirin (acetylsalicylic acid), paracetamol; narcotic — morphine
AntipyreticReduces feverParacetamol, aspirin
AntibioticKills bacteria / stops their growth (no effect on viruses)Penicillin (Alexander Fleming, 1928), streptomycin, chloramphenicol
AntacidStomach acidityMg(OH)₂ (milk of magnesia), NaHCO₃, ranitidine
AntisepticOn living tissue (wounds)Dettol (chloroxylenol + terpineol), tincture of iodine, boric acid; 0.2% phenol
DisinfectantOn non-living things (floors, drains)1% phenol, chlorine (0.2–0.4 ppm in water), bleaching powder
TranquilizerStress/sleepValium, barbiturates
Artificial sweetenerFor diabetes patientsSaccharin (~550 times sweeter), aspartame (breaks down on heating — only in cold foods), sucralose
  • Aspirin (the acetyl form of salicylic acid) — the acetyl group reduces gastric irritation while the pain-relieving/anti-inflammatory properties remain; it thins the blood (helps prevent heart attacks). Salicylic acid itself harms the stomach more.
⚠️ Vyapam Alert (Exam Traps):
  • Sucrose = non-reducing (Fehling test negative); glucose, fructose, maltose, lactose = reducing.
  • Antibiotics do not work on viruses (common cold, COVID).
  • Same phenol: 0.2% = antiseptic, 1% = disinfectant.
  • Basis of enzyme classification = type of reaction.
🎯 Official PYQs (MPESB SI Prelims 2025):
Q1. Why is acetylsalicylic acid (aspirin) more effective as a painkiller than salicylic acid?MPESB SI Prelims 2025 — 16 Jan 2026, Shift 2
(1) Acetylsalicylic acid has a lower pKa value
(2) The acetyl group reduces gastric irritation while keeping the anti-inflammatory properties
(3) Acetylsalicylic acid is more soluble in water
(4) The ester linkage makes it more stable at body temperature
Correct answer: (2)
Explanation: Salicylic acid badly irritates the inner lining of the stomach. Its acetyl form (aspirin) causes less irritation, and inside the body it gives the same pain-relieving / anti-inflammatory effect.
Q2. On what basis are enzymes classified into six major classes?MPESB SI Prelims 2025 — 17 Jan 2026, Shift 2
(1) Their molecular weight and subunit structure
(2) The type of chemical reaction they catalyse
(3) Their cellular location and distribution
(4) Their cofactor requirements
Correct answer: (2)
Explanation: Oxidoreductase (redox), transferase (group transfer), hydrolase (hydrolysis), lyase, isomerase, ligase — the names themselves are based on the type of reaction.
Q3. What helps in classifying amino acids as essential and non-essential?MPESB SI Prelims 2025 — 18 Jan 2026, Shift 1
(1) Their chemical structure and functional groups
(2) Their role in protein structure
(3) The body's ability to synthesise them from other compounds
(4) Their solubility in water
Correct answer: (3)
Explanation: An amino acid the body cannot make = essential (must be taken from food); one the body can make = non-essential.
Q4. Why do some monosaccharides lose their reducing property when forming a glycosidic bond?MPESB SI Prelims 2025 — 19 Jan 2026, Shift 1
(1) The carbonyl carbon becomes part of an acetal linkage
(2) The ring structure blocks access to the anomeric carbon
(3) Oxidation is prevented by steric hindrance from the glycosidic partner
(4) The electron density around the carbonyl carbon gets redistributed
Correct answer: (1)
Explanation: The reducing property needs a free carbonyl (anomeric) carbon that can open the ring and give an aldehyde/ketone. In a glycosidic bond, that same carbon becomes an acetal → the ring does not open → it does not reduce Fehling/Tollens (e.g. sucrose).
✍️ Practice MCQs (self-made, not PYQs):
P1. Who discovered penicillin?
(A) Louis Pasteur
(B) Edward Jenner
(C) Alexander Fleming
(D) Robert Koch
Answer: (C) Alexander Fleming (1928)
P2. Which of the following sugars is non-reducing?
(A) Glucose
(B) Maltose
(C) Sucrose
(D) Lactose
Answer: (C) Sucrose
P3. 'Milk of magnesia' is used as:
(A) Antibiotic
(B) Antacid
(C) Antiseptic
(D) Analgesic
Answer: (B) Antacid — Mg(OH)₂.

📌 11. Noble Gases, Hydrogen, Air & Radioactivity (6 min read)

11.1 Noble / Inert Gases (Group 18)

GasUses / Fact
Helium (He)Light, non-flammable → balloons, airships; He + O₂ mixture — deep-sea divers (dissolves less in blood than N₂); liquid He — lowest boiling point, cryogenics (MRI magnets)
Neon (Ne)Advertising neon signs (orange-red glow)
Argon (Ar)Most abundant noble gas in air (~0.93%); filled in electric bulbs (protects the filament from oxidation); welding
Krypton (Kr), Xenon (Xe)High-intensity lamps, camera flash. First noble gas compound — XePtF₆ (Neil Bartlett, 1962)
Radon (Rn)Radioactive; cancer radiotherapy
  • These gases are almost inert because their outer shell is completely filled (2 electrons in He, 8 in the others).

11.2 Hydrogen, Water & Air

  • Hydrogen — the lightest element, the most abundant in the universe. Isotopes: protium, deuterium, tritium.
  • Hardness of water: temporary — bicarbonates of Ca/Mg → removed by boiling; permanent — chlorides/sulphates of Ca/Mg → removed by washing soda or ion-exchange.
  • Dry air: Nitrogen ~78%, Oxygen ~21%, Argon ~0.93%, CO₂ ~0.04%.
  • Ozone (O₃) layer — in the stratosphere; absorbs the Sun's UV rays. CFCs (chlorofluorocarbons) — fridge/AC gases — destroy it. Montreal Protocol (1987).
  • Greenhouse gases: CO₂, methane (CH₄), N₂O, CFCs, water vapour → global warming. Acid rain — SO₂ and NOₓ.

11.3 Radioactivity

  • Discovery: Henri Becquerel (1896) — in uranium. Marie & Pierre Curie — discovered polonium and radium; Marie Curie — Nobel in two different subjects (Physics 1903, Chemistry 1911).
  • SI unit: becquerel (Bq); old unit: curie (Ci).
RayWhat it isChargePenetrationIonisation
Alpha (α)Helium nucleus (2p + 2n)+2Lowest (stopped by paper)Highest
Beta (β)Fast electrons−1Medium (thin aluminium sheet)Medium
Gamma (γ)Electromagnetic radiation (photons)0Highest (needs thick lead)Lowest
  • Half-life: the time in which half of the radioactive nuclei decay.
  • Carbon dating — age of fossils/old wood from C-14 (half-life ~5730 years) (W.F. Libby).
  • Uses: Cobalt-60 — cancer treatment; Iodine-131 — thyroid; Uranium-235 — fuel of nuclear reactors.
⚠️ Vyapam Alert (Exam Traps):
  • In bulbs = Argon; neon sign = Neon; balloons/divers = Helium; radioactive = Radon.
  • Penetration: γ > β > α; Ionisation: α > β > γ (reverse order).
  • Most abundant gas in air = Nitrogen (not Oxygen).
✍️ Practice MCQs (self-made, not PYQs):
P1. Which inert gas is usually filled in electric bulbs?
(A) Helium
(B) Neon
(C) Argon
(D) Radon
Answer: (C) Argon
P2. Which radiation has the highest penetrating power?
(A) Alpha
(B) Beta
(C) Gamma
(D) All equal
Answer: (C) Gamma
P3. Who discovered radioactivity?
(A) Marie Curie
(B) Henri Becquerel
(C) Rutherford
(D) Roentgen
Answer: (B) Henri Becquerel (1896)
P4. Deep-sea divers use a mixture of oxygen with which gas for breathing?
(A) Nitrogen
(B) Helium
(C) Argon
(D) Hydrogen
Answer: (B) Helium

PYQ source: official MPESB SI Prelims 2025 paper (16–21 Jan 2026, 12 shifts)