Answer Review — Mock Test
JEE Main · 11 Jun 2026
x = 4y $-$ 2 & x^{2} = 4y
$ \Rightarrow $ x^{2} = x + 2 $ \Rightarrow $ x^{2} $-$ x $-$ 2 = 0
x = 2, $-$ 1
So, $\int\limits_{ - 1}^2 {\left( {{{x + 2} \over 4} - {{{x^2}} \over 4}} \right)\,dx = {9 \over 8}} $
The equation of the plane passing through points $A(-1, -2, -3)$, $B(9, 3, 4)$, and $C(9, -2, 1)$ can be written using the determinant :
$ \left|\begin{array}{ccc} x+1 & y+2 & z+3 \\ 10 & 5 & 7 \\ 10 & 0 & 4 \end{array}\right|=0 $
Expanding the determinant, we get :
$ 2x + 3y - 5z - 7 = 0 $
Next, we find the foot of the perpendicular from point $P(3, -2, -9)$ to the plane. Using the coordinates of $P$ and the equation of the plane, we can find the ratio of the perpendicular distance to the sum of the squares of the coefficients of $x$, $y$, and $z$ :
$ \frac{2(3) + 3(-2) - 5(-9) - 7}{2^2 + 3^2 + (-5)^2} = \frac{-38}{38} $
We can now find the coordinates of the foot of the perpendicular, $Q(\alpha, \beta, \gamma)$ :
$ \frac{\alpha - 3}{2} = \frac{\beta + 2}{3} = \frac{\gamma + 9}{-5} = -\frac{38}{38} $
Solving for $\alpha$, $\beta$, and $\gamma$ :
$ \alpha = 3 - 2\left(-\frac{38}{38}\right) = 1 $
$ \beta = -2 + 3\left(-\frac{38}{38}\right) = -5 $
$ \gamma = -9 - 5\left(-\frac{38}{38}\right) = -4 $
So, the coordinates of the foot of the perpendicular are $Q(1, -5, -4)$. Now, we can find the distance of point $Q$ from the origin :
$ OQ = \sqrt{\alpha^2 + \beta^2 + \gamma^2} = \sqrt{1^2 + (-5)^2 + (-4)^2} = \sqrt{42} $
The value of $\log _{e} 2 \frac{d}{d x}\left(\log _{\cos x} \operatorname{cosec} x\right)$ at $x=\frac{\pi}{4}$ is
Let $f(x) = {\log _{\cos x}}\cos ec\,x$
$ = {{\log \cos ec\,x} \over {\log \cos x}}$
$ \Rightarrow f'(x) = {{\log \cos x\,.\,\sin x\,.\,\left( { - \cos ec\,x\cot x - \log \cos ec\,x\,.\,{1 \over {\cos x}}\,.\, - \sin x} \right)} \over {{{(\log \cos x)}^2}}}$
at $x = {\pi \over 4}$
$f'\left( {{\pi \over 4}} \right) = {{ - \log \left( {{1 \over {\sqrt 2 }}} \right) + \log \sqrt 2 } \over {{{\left( {\log {1 \over {\sqrt 2 }}} \right)}^2}}} = {2 \over {\log \sqrt 2 }}$
$\therefore$ ${\log _e}2f'(x)$ at $x = {\pi \over 4} = 4$
The lines $\frac{x-2}{2}=\frac{y}{-2}=\frac{z-7}{16}$ and $\frac{x+3}{4}=\frac{y+2}{3}=\frac{z+2}{1}$ intersect at the point $P$. If the distance of $\mathrm{P}$ from the line $\frac{x+1}{2}=\frac{y-1}{3}=\frac{z-1}{1}$ is $l$, then $14 l^2$ is equal to __________.
$\begin{aligned} & \frac{\mathrm{x}-2}{1}=\frac{\mathrm{y}}{-1}=\frac{\mathrm{z}-7}{8}=\lambda \\ & \frac{\mathrm{x}+3}{4}=\frac{\mathrm{y}+2}{3}=\frac{\mathrm{z}+2}{1}=\mathrm{k} \\ & \Rightarrow \lambda+2=4 \mathrm{k}-3 \\ & -\lambda=3 \mathrm{k}-2 \\ & \Rightarrow \mathrm{k}=1, \lambda=-1 \\ & 8 \lambda+7=\mathrm{k}-2 \\ & \therefore \mathrm{P}=(1,1,-1) \end{aligned}$

Projection of $2 \hat{i}-2 \hat{k}$ on $2 \hat{i}+3 \hat{j}+\hat{k}$ is
$\begin{aligned} & =\frac{4-2}{\sqrt{4+9+1}}=\frac{2}{\sqrt{14}} \\ & \therefore l^2=8-\frac{4}{14}=\frac{108}{14} \\ & \Rightarrow 14 l^2=108 \end{aligned}$
Let $f:[2,4] \rightarrow \mathbb{R}$ be a differentiable function such that $\left(x \log _{e} x\right) f^{\prime}(x)+\left(\log _{e} x\right) f(x)+f(x) \geq 1, x \in[2,4]$ with $f(2)=\frac{1}{2}$ and $f(4)=\frac{1}{4}$.
Consider the following two statements :
(A) : $f(x) \leq 1$, for all $x \in[2,4]$
(B) : $f(x) \geq \frac{1}{8}$, for all $x \in[2,4]$
Then,
Let the operations $*, \odot \in\{\wedge, \vee\}$. If $(\mathrm{p} * \mathrm{q}) \odot(\mathrm{p}\, \odot \sim \mathrm{q})$ is a tautology, then the ordered pair $(*, \odot)$ is :
$ * ,\, \odot \in \{ \wedge ,\, \vee \} $
Now for $(p * q) \odot (p \odot \sim q)$ is tautology
(A) $( \vee , \wedge ):(p \vee q) \wedge (p \wedge \sim q)$ not a tautology
(B) $( \vee , \vee ):(p \vee q) \vee (p \vee \sim q)$
$ = P \vee T$ is tautology
(C) $( \wedge , \wedge ):(p \wedge q) \wedge (p \wedge \sim q)$
$ = (p \wedge p) \wedge (q \wedge \sim q) = p \wedge F$ not a tautology (Fallasy)
(D) $( \wedge , \vee ):(p \wedge q) \vee (p \vee \sim q)$ not a tautology

Let $M = \left[ {\matrix{ 0 & { - \alpha } \cr \alpha & 0 \cr } } \right]$, where $\alpha$ is a non-zero real number an $N = \sum\limits_{k = 1}^{49} {{M^{2k}}} $. If $(I - {M^2})N = - 2I$, then the positive integral value of $\alpha$ is ____________.
Area = 2 $ \times $ ${1 \over 2}$.4 = 2
The probability, of forming a 12 persons committee from 4 engineers, 2 doctors and 10 professors containing at least 3 engineers and at least 1 doctor, is
$\begin{array}{lll} 3 E, & 1 D, & 8 P \\ 3 E, & 2 D, & 7 P \\ 4 E, & 1 D, & 7 P \\ 4 E, & 2 D, & 6 P \end{array}$
$\begin{aligned} & P=\frac{{ }^4 C_3 \cdot{ }^2 C_1 \cdot{ }^{10} C_8+{ }^4 C_3 \cdot{ }^2 C_2 \cdot{ }^{10} C_7+{ }^4 C_4 \cdot{ }^2 C_1 \cdot{ }^{10} C_7+{ }^4 C_4 \cdot{ }^2 C_2 \cdot{ }^{10} C_6}{{ }^{10} C_{12}} \\ & =\frac{129}{182} \end{aligned}$
Let $\int_\limits\alpha^{\log _e 4} \frac{\mathrm{d} x}{\sqrt{\mathrm{e}^x-1}}=\frac{\pi}{6}$. Then $\mathrm{e}^\alpha$ and $\mathrm{e}^{-\alpha}$ are the roots of the equation :
$\begin{aligned} & \text { Let } \sqrt{e^x-1}=t \\ & e^x-1=t^2 \\ & e^x=1+t^2 \\ & e^x=0+2 t-\frac{d t}{d x} \\ & \frac{d t}{d x}=\frac{e^x}{2 t}=\frac{t^2+1}{2 t} \\ & I=\int \frac{2 t}{t\left(1+t^2\right)} d t=2 \tan ^{-1} t \\ & \Rightarrow \quad I=\int_\limits\alpha^{\log ^4} \frac{d x}{\sqrt{e^x-1}} \\ & I=\left.2 \tan ^{-1} \sqrt{e^x-1}\right|_\alpha ^{\log 4} \\ & =2\left(\tan ^{-1} \sqrt{3}-\tan ^{-1} \sqrt{e^\alpha-1}\right)=\frac{\pi}{6} \\ & \Rightarrow \frac{\pi}{3}-\tan ^{-1}\left(\sqrt{e^\alpha-1}\right)=\frac{\pi}{12} \\ & \tan ^{-1}\left(\sqrt{e^\alpha-1}\right)=\frac{\pi}{4} \\ & \Rightarrow e^\alpha-1=1 \\ & e^\alpha=2 \Rightarrow e^{-\alpha}=\frac{1}{2} \end{aligned}$
$\therefore \quad$ Quadratic equation whose roots are $e^a$ & $e^{-\alpha}$ is
$\begin{aligned} & x^2-\left(e^\alpha+e^{-\alpha}\right) x+e^\alpha \times e^{-\alpha}=0 \\ & x^2-\left(2+\frac{1}{2}\right) x+1=0 \\ & 2 x^2-5 x+2=0 \end{aligned}$
Two satellites S_{1} and S_{2} are revolving in circular orbits around a planet with radius R_{1} = 3200 km and R_{2} = 800 km respectively. The ratio of speed of satellite S_{1} to be speed of satellite S_{2} in their respective orbits would be ${1 \over x}$ where x = ___________.
$v = \sqrt {{{GM} \over R}} $
$ \Rightarrow {{{v_1}} \over {{v_2}}} = \sqrt {{{{R_2}} \over {{R_1}}}} $
${{{v_2}} \over {{v_1}}} = \sqrt {{{3200} \over {800}}} = 2$
$ \Rightarrow {{{v_1}} \over {{v_2}}} = {1 \over 2}$
$x = 2$
Match the List I with List II
| List - I | List - II | ||
|---|---|---|---|
| (A) | Triatomic rigid gas | (I) | $\frac{C_p}{C_v}=\frac{5}{3}$ |
| (B) | Diatomic non-rigid gas | (II) | $\frac{C_p}{C_v}=\frac{7}{5}$ |
| (C) | Monoatomic gas | (III) | $\frac{C_p}{C_v}=\frac{4}{3}$ |
| (D) | Diatomic rigid gas | (IV) | $\frac{C_p}{C_v}=\frac{9}{7}$ |
Choose the correct answer from the options given below:
The explanation uses the equation for the heat capacity ratio, $ \gamma = 1 + \frac{2}{\text{f}} $, where $ \text{f} $ is the degrees of freedom of the gas. Here's how it applies to different types of gases:
Triatomic Rigid Gas:
Degrees of freedom ($ \text{f} $) = 6
$ \gamma = 1 + \frac{2}{6} = \frac{4}{3} $
Diatomic Non-Rigid Gas:
Degrees of freedom ($ \text{f} $) = 7
$ \gamma = 1 + \frac{2}{7} = \frac{9}{7} $
Diatomic Rigid Gas:
Degrees of freedom ($ \text{f} $) = 5
$ \gamma = 1 + \frac{2}{5} = \frac{7}{5} $
Monoatomic Gas:
Degrees of freedom ($ \text{f} $) = 3
$ \gamma = 1 + \frac{2}{3} = \frac{5}{3} $
Therefore, when matching List I with List II, the correct pairing is:
A (Triatomic rigid gas) - III $(\frac{4}{3})$
B (Diatomic non-rigid gas) - IV $(\frac{9}{7})$
C (Monoatomic gas) - I $(\frac{5}{3})$
D (Diatomic rigid gas) - II $(\frac{7}{5})$
Thus, the correct answer from the options given is:
A-III, B-IV, C-I, D-II
A vertical electric field of magnitude 4.9 $\times$ 10^{5} N/C just prevents a water droplet of a mass 0.1 g from falling. The value of charge on the droplet will be :
(Given : g = 9.8 m/s^{2})
Since the droplet is at rest
$\Rightarrow$ Net force = 0
$\Rightarrow$ mg = qE
$\Rightarrow$ $q = {{mg} \over E}$ = 2 $\times$ 10^{$-$9} C
Different combination of 3 resistors of equal resistance $\mathrm{R}$ are shown in the figures. The increasing order for power dissipation is:

Electron beam used in an electron microscope, when accelerated by a voltage of 20 kV, has a de-Broglie wavelength of $\lambda_0$. IF the voltage is increased to 40 kV, then the de-Broglie wavelength associated with the electron beam would be :
Let $B_1$ be the magnitude of magnetic field at center of a circular coil of radius $R$ carrying current I. Let $\mathrm{B}_2$ be the magnitude of magnetic field at an axial distance ' $x$ ' from the center. For $x: \mathrm{R}=3: 4, \frac{\mathrm{~B}_2}{\mathrm{~B}_1}$ is :

$\begin{aligned} & B_1=\frac{\mu_0 i}{2 R} \quad \quad B_2=B_1 \sin ^3 \theta \\ & \therefore \frac{B_2}{B_1}=\sin ^3 \theta=\left(\frac{4}{5}\right)^3=\frac{64}{125} \end{aligned}$
In the given circuit, the equivalent resistance between the terminal A and B is __________ $\Omega$.


$
\begin{aligned}
& \mathrm{R}_{\mathrm{eq}}=3+(2 \| 2)+6 \\\\
& \mathrm{R}_{\mathrm{eq}}=3+1+6 \\\\
& \mathrm{R}_{\mathrm{eq}}=10 \Omega
\end{aligned}
$

A bar magnet has total length $2 l=20$ units and the field point P is at a distance $\mathrm{d}=10$ units from the centre of the magnet. If the relative uncertainty of length measurement is $1 \%$, then uncertainty of the magnetic field at point P is :
To determine the uncertainty of the magnetic field at point P, we consider two approaches:
Without considering uncertainty in length $\ell$:
The magnetic field $ B $ at point P is given by:
$ B = \frac{\mu_0}{4 \pi} \frac{m}{r^3} $
Where $ B $ is inversely proportional to $ r^3 $:
$ B \propto \frac{1}{r^3} $
The relative uncertainty in $ B $, expressed as a percentage, is calculated by:
$ \frac{\Delta B}{B} = 3 \times \left(\frac{\Delta r}{r}\right) $
Given that the relative uncertainty in length measurement is $1\%$, the uncertainty in $ B $ becomes:
$ \% \text{ uncertainty in } B = 3 \% $
Method-2: Considering uncertainty in length $\ell$:
Here, we also account for the uncertainty in $\ell$:
$ B \propto \frac{1}{r^3} $
Thus, the combined relative uncertainty, incorporating $\ell$, is:
$ \frac{\Delta B}{B} = \frac{\Delta \ell}{\ell} + 3 \times \left(\frac{\Delta r}{r}\right) $
Substituting the given uncertainties:
$ \frac{\Delta B}{B} = 1 + 3 \times 1 = 4\% $
Therefore, the percentage uncertainty in $ B $, considering the length $\ell$, is $4\%$.
In the following circuit, the magnitude of current I_{1}, is ___________ A.

The indicated diagram shows current flow diagram loops for writing Kirchhoff's law are also indicated, writing the equation

$2{I_3} + {I_1} + {I_3} + {I_2} = 5$
or ${I_1} + {I_2} + 3{I_3} = 5$ ..... (1)
${I_2} - 5 = 2({I_3} - {I_2}) + ({I_1} + {I_3} - {I_2})$
or ${I_1} - 4{I_2} + 3{I_3} = - 5$ ...... (2)
$({I_1} + {I_3}) + ({I_1} + {I_3} - {I_2}) = 2$
or $2{I_1} - {I_2} + 2{I_3} = 2$ ...... (3)
on solving ${I_1} = {3 \over 2}A,{I_2} = 2,{I_3} = {1 \over 2}A$
$ = 1.50$
A sample of gas at temperature $T$ is adiabatically expanded to double its volume. The work done by the gas in the process is $\left(\mathrm{given}, \gamma=\frac{3}{2}\right)$ :
Two uniformly charged spherical conductors $A$ and $B$ of radii $5 \mathrm{~mm}$ and $10 \mathrm{~mm}$ are separated by a distance of $2 \mathrm{~cm}$. If the spheres are connected by a conducting wire, then in equilibrium condition, the ratio of the magnitudes of the electric fields at the surface of the sphere $A$ and $B$ will be :
After connection
${\sigma _1}{R_1} = {\sigma _2}{R_2}$
Now $E = {\sigma \over {{\varepsilon _0}}}$
$ \Rightarrow {{{E_1}} \over {{E_2}}} = {{{\sigma _1}} \over {{\sigma _2}}} = {{{R_2}} \over {{R_1}}} = {2 \over 1}$
Given below are two statements : one is labelled as Assertion A and the other is labelled as Reason R
Assertion A : When a body is projected at an angle $45^{\circ}$, it's range is maximum.
Reason R : For maximum range, the value of $\sin 2 \theta$ should be equal to one.
In the light of the above statements, choose the correct answer from the options given below:
The Boolean expression $\mathrm{Y}=A \bar{B} C+\bar{A} \bar{C}$ can be realised with which of the following gate configurations.
A. One 3-input AND gate, 3 NOT gates and one 2-input OR gate, One 2-input AND gate,
B. One 3 -input AND gate, 1 NOT gate, One 2 -input NOR gate and one 2 -input OR gate
C. 3 -input OR gate, 3 NOT gates and one 2 -input AND gate
Choose the correct answer from the options given below:

$\because \overline{\mathrm{A}} \cdot \overline{\mathrm{C}}+\overline{\mathrm{A}+\mathrm{C}} \equiv$ NOR gate
Two blocks of masses 10 kg and 30 kg are placed on the same straight line with coordinates (0, 0) cm and (x, 0) cm respectively. The block of 10 kg is moved on the same line through a distance of 6 cm towards the other block. The distance through which the block of 30 kg must be moved to keep the position of centre of mass of the system unchanged is :
For COM to remain unchanged,
m_{1}x_{1} = m_{2}x_{2}
$\Rightarrow$ 10 $\times$ 6 = 30 $\times$ x_{2}
$\Rightarrow$ x_{2} = 2 cm towards 10 kg block.
The momentum of an electron revolving in $\mathrm{n}^{\text {th }}$ orbit is given by :
(Symbols have their usual meanings)
$\because$ $mvr = {{nh} \over {2\pi }}$
$ \Rightarrow mv = {{nh} \over {2\pi r}}$
In an electromagnetic system, a quantity defined as the ratio of electric dipole moment and magnetic dipole moment has dimension of $\left[\mathrm{M}^{\mathrm{P}} \mathrm{L}^{\mathrm{Q}} \mathrm{T}^R A^{\mathrm{S}}\right]$. The value of P and Q are :
Electric dipole moment $(\overrightarrow{\mathrm{P}})=\mathrm{q} \times 2 \ell$
Magnetic dipole moment $(\overrightarrow{\mathrm{M}})=\mathrm{IA}$
$\left[\frac{\mathrm{P}}{\mathrm{M}}\right]=\left[\frac{\mathrm{LTA}}{\mathrm{~L}^2 \mathrm{~A}}\right]=\mathrm{L}^{-1} \mathrm{~T}=\mathrm{M}^0 \mathrm{~L}^{-1} \mathrm{~T}^1 \mathrm{~A}^0$
After compering values of $\mathrm{P} \& \mathrm{Q}$ are $0,-1$
Correct Answer : Option 4

Potential Difference across each resistor = 2V
q = CV
= 50 $\times$ 10^{$-$6} $\times$ 2 = 100 $\times$ 10^{$-$6} = 100 $\mu$C
$0.08 \mathrm{~kg}$ air is heated at constant volume through $5^{\circ} \mathrm{C}$. The specific heat of air at constant volume is $0.17 \mathrm{~kcal} / \mathrm{kg}^{\circ} \mathrm{C}$ and $\mathrm{J}=4.18$ joule/$\mathrm{~cal}$. The change in its internal energy is approximately.
To find the change in the internal energy of air when it is heated at constant volume, we use the formula for heat transfer at constant volume, which is given by:
$\Delta U = m c_v \Delta T$
Where:
- $\Delta U$ is the change in internal energy,
- $m$ is the mass of the substance (in this case, air),
- $c_v$ is the specific heat at constant volume,
- $\Delta T$ is the change in temperature.
Given that:
- The mass of air, $m = 0.08 \, \text{kg},$
- The specific heat of air at constant volume, $c_v = 0.17 \, \text{kcal/kg}^{\circ}\text{C},$
- The change in temperature, $\Delta T = 5^{\circ} \text{C},$
- And the conversion factor from calories to Joules, $1 \, \text{cal} = 4.18 \, \text{J}.$
First, convert the specific heat from kcal to Joules:
$c_v = 0.17 \, \text{kcal/kg}^{\circ}\text{C} \times 1000 \, \text{cal/kcal} \times 4.18 \, \text{J/cal} = 710.6 \, \text{J/kg}^{\circ}\text{C}$
Now, substitute the values into the formula:
$\Delta U = 0.08 \times 710.6 \times 5$
$\Delta U = 284 \, \text{J}$
Thus, the change in internal energy is approximately 284 Joules.
A square loop of side $15 \mathrm{~cm}$ being moved towards right at a constant speed of $2\mathrm{~cm} / \mathrm{s}$ as shown in figure. The front edge enters the $50 \mathrm{~cm}$ wide magnetic field at $t=0$. The value of induced emf in the loop at $t=10 \mathrm{~s}$ will be :

Time taken to cross the field region
$=\frac{50}{2}=25 \mathrm{~s}$
At $10 \mathrm{~s}$ the loop is inside field and flux is not changing.
$\therefore \quad \varepsilon_{\text {induced }}=0$
The energy released per fission of nucleus of $^{240}$X is 200 MeV. The energy released if all the atoms in 120g of pure $^{240}$X undergo fission is ____________ $\times$ 10$^{25}$ MeV.
(Given $\mathrm{N_A=6\times10^{23}}$)
Sand is being dropped from a stationary dropper at a rate of $0.5 \,\mathrm{kgs}^{-1}$ on a conveyor belt moving with a velocity of $5 \mathrm{~ms}^{-1}$. The power needed to keep the belt moving with the same velocity will be :
${{dm} \over {dt}} = 0.5$ kg/s
$v = 5$ m/s
$F = {{vdm} \over {dt}} = 2.5$ kg m/s^{2}
$P = \overline F \,.\,\overline v = (2.5)(5)$ W
$ = 12.5$ W
Among the following, basic oxide is :
Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R.
Assertion A: $\mathrm{LiF}$ is sparingly soluble in water.
Reason R: The ionic radius of $\mathrm{Li}^{+}$ ion is smallest among its group members, hence has least hydration enthalpy.
In the light of the above statements, choose the most appropriate answer from the options given below.
Which of the following options are correct for the reaction
$2\left[\mathrm{Au}(\mathrm{CN})_{2}\right]^{-}(\mathrm{aq})+\mathrm{Zn}(\mathrm{s}) \rightarrow 2 \mathrm{Au}(\mathrm{s})+\left[\mathrm{Zn}(\mathrm{CN})_{4}\right]^{2-}(\mathrm{aq})$
A. Redox reaction
B. Displacement reaction
C. Decomposition reaction
D. Combination reaction
Choose the correct answer from the options given below:
Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).
Assertion (A) : Dissolved substances can be removed from a colloidal solution by diffusion through a parchment paper.
Reason (R) : Particles in a true solution cannot pass through parchment paper but the colloidal particles can pass through the parchment paper.
In the light of the above statements, choose the correct answer from the options given below :
$K = {{[C]_{eq}^2} \over {{{[A]}_{eq}}{{[B]}_{eq}}}} = {{{{(1 + 2x)}^2}} \over {(1 - x)(1 - x)}}$
$100 = {\left( {{{1 + 2x} \over {1 - x}}} \right)^2}$
$\left( {{{1 + 2x} \over {1 - x}}} \right) = 10$
$x = {3 \over 4}$
$[C]{e_{q.}} = 1 + 2x$
$ = 1 + 2\left( {{3 \over 4}} \right)$
= 2.5 M
= 25 $\times$ 10^{-1} M
To determine the solubility product (K_{sp}) of calcium phosphate, we need to consider its chemical formula and how it dissociates in water. The formula for calcium phosphate is $\text{Ca}_3(\text{PO}_4)_2$. When dissolved in water, it dissociates according to the following equation:
$ \text{Ca}_3(\text{PO}_4)_2 (s) \rightleftharpoons 3 \text{Ca}^{2+} (aq) + 2 \text{PO}_4^{3-} (aq) $
Let $S$ be the molar solubility of calcium phosphate in $\text{mol}/L$. According to the stoichiometry of the dissociation, if $S$ moles per liter of calcium phosphate dissolve, $3S$ moles per liter of calcium ions and $2S$ moles per liter of phosphate ions are produced.
The expression for the solubility product constant (Ksp) for calcium phosphate in water is the product of the concentrations of the ions raised to the power of their respective coefficients in the balanced equation:
$ K_{sp} = [\text{Ca}^{2+}]^3 [\text{PO}_4^{3-}]^2 $
Substituting the concentrations with $3S$ for $\text{Ca}^{2+}$ and $2S$ for $\text{PO}_4^{3-}$, we get:
$ K_{sp} = (3S)^3 (2S)^2 = 27S^3 \cdot 4S^2 = 108S^5 $
If the solubility of calcium phosphate is $\text{W}_{g}$ per $100 \text{ mL}$ of water at $25^\circ\text{C}$, we need to convert grams to moles to find $S$. Solubility in moles per liter (which is the same as moles per $1000 \text{ mL}$) is:
$ S = \frac{\text{W}}{\text{M}} \times \frac{1000 \text{ mL}}{100 \text{ mL}} = 10\frac{\text{W}}{\text{M}} $
Now, substituting $S$ with $10\frac{\text{W}}{\text{M}}$ into the expression for $K_{sp}$:
$ K_{sp} = 108 \left(10\frac{\text{W}}{\text{M}}\right)^5 $
This simplifies to:
$ K_{sp} = 108 \times 10^5 \left(\frac{\text{W}}{\text{M}}\right)^5 $
Since $108$ is on the order of $10^2$, we can approximate this to:
$ K_{sp} \approx 10^7 \left(\frac{\text{W}}{\text{M}}\right)^5 $
Therefore, the correct answer based on the options provided is:
Option C: $10^7 \left(\frac{\text{W}}{\text{M}}\right)^5$
Given below are two statements:
Statement I: In group 13, the stability of +1 oxidation state increases down the group.
Statement II : The atomic size of gallium is greater than that of aluminium.
In the light of the above statements, choose the most appropriate answer from the options given below :
Statement I:
"In group 13, the stability of +1 oxidation state increases down the group."
Analysis:
Group 13 Elements:
Boron (B)
Aluminum (Al)
Gallium (Ga)
Indium (In)
Thallium (Tl)
Common Oxidation States:
The typical oxidation state for group 13 elements is +3.
However, due to the inert pair effect, the +1 oxidation state becomes more stable as we move down the group.
Inert Pair Effect:
The reluctance of the s-electrons (ns²) in the valence shell to participate in bonding.
This effect becomes more significant in heavier elements due to poor shielding by inner d and f orbitals.
Stability Trend:
Boron (B): Exhibits only the +3 oxidation state.
Aluminum (Al): Predominantly +3 oxidation state.
Gallium (Ga): +3 is more stable, but +1 oxidation state starts appearing.
Indium (In): +1 oxidation state becomes significant.
Thallium (Tl): The +1 oxidation state is more stable than the +3 oxidation state.
Conclusion for Statement I:
Correct.
The stability of the +1 oxidation state increases as we move down group 13 due to the inert pair effect.
Statement II:
"The atomic size of gallium is greater than that of aluminium."
Analysis:
Expected Trend:
Generally, atomic size increases down a group because each successive element has an additional electron shell.
Actual Atomic Radii:
Aluminum (Al): Approximately 143 picometers (pm)
Gallium (Ga): Approximately 135 pm
Anomalous Behavior:
**Gallium's atomic radius is *slightly smaller* than that of aluminum.**
This anomaly is due to the presence of 10 d-electrons in gallium's electron configuration (Ga: [Ar] 3d¹⁰ 4s² 4p¹).
Poor Shielding Effect:
3d electrons do not shield the nuclear charge effectively.
As a result, the effective nuclear charge increases, pulling the outer electrons closer to the nucleus.
This causes gallium to have a smaller atomic radius compared to aluminum.
Conclusion for Statement II:
Incorrect.
The atomic size of gallium is less than that of aluminum due to poor shielding by d-electrons.
Final Answer:
Statement I is correct, as the stability of the +1 oxidation state increases down group 13.
Statement II is incorrect, because gallium has a smaller atomic radius than aluminum.
Answer: Option B
Correct statements for the given reaction are :

A. Compound '$\mathrm{B}$' is aromatic
B. The completion of above reaction is very slow
C. 'A' shows tautomerism
D. The bond lengths of C-C in compound $B$ are found to be same
Choose the correct answer from the options given below:
Resonance hybrid of B showing all C-C bond length same
$\to$ 10 $\pi$e^{$-$} in cyclic conjugation
$\Rightarrow$ Aromatic
"Note: For a compound with multiple cyclic rings to exhibit aromaticity, it must conform to Hückel's rule, which stipulates that the molecule should have (4n+2) π-electrons in the largest periphery of continuous conjugation. Rings with sp^{3} hybridized carbon atoms are not considered in this context. Despite their potential π-bonds, these rings cannot participate in resonance with π-bonds of the other rings due to the sp^{3} hybridization, and thus do not contribute to the overall aromaticity of the compound."
(b)
$\to$ 4 $\pi$e^{$-$} in ring conjugation $\Rightarrow$ Anti Aromatic
(c)
$\Rightarrow$ 4 $\pi$e^{$-$} in ring conjugation $\Rightarrow$ Antiaromatic
(d)
6$\pi$e^{$-$} in ring conjugation $\Rightarrow$ Aromatic
Identify the major product in the following reaction.


The depression in freezing point observed for a formic acid solution of concentration $0.5 \mathrm{~mL} \mathrm{~L}^{-1}$ is $0.0405^{\circ} \mathrm{C}$. Density of formic acid is $1.05 \mathrm{~g} \mathrm{~mL}^{-1}$. The Van't Hoff factor of the formic acid solution is nearly : (Given for water $\mathrm{k}_{\mathrm{f}}=1.86\, \mathrm{k} \,\mathrm{kg}\,\mathrm{mol}^{-1}$ )

Residue (A) + HCl (dil) $\rightarrow$ Compound (B)
Structure of residue (A) and compound (B) formed respectively is :
The minimum energy that must be possessed by photons in order to produce the photoelectric effect with platinum metal is :
[Given : The threshold frequency of platinum is 1.3 $\times$ 10^{15} s^{$-$1} and h = 6.6 $\times$ 10^{$-$34} J s.]
The minimum energy possessed by photons will be equal to the work function of the metal.
$ \therefore $ E_{min} = h$\nu $_{0} J
= 6.6 $\times$ 10^{$-$34} $ \times $ 1.3 $\times$ 10^{15}
= 8.58 $\times$ 10^{$-$19} J
$ \text { Match the LIST-I with LIST-II } $
| LIST-I (Family) | LIST-II (Symbol of Element) | ||
|---|---|---|---|
| A. | Pnictogen (group 15) | I | Ts |
| B | Chalcogen | II | Og |
| C | Halogen | III | Lv |
| D | Noble gas | IV | Mc |
To correctly match the elements with their respective families and symbols, consider the following associations:
Pnictogen is matched with Moscovium (Mc), which has the atomic number 115.
Chalcogen corresponds to Livermorium (Lv), with the atomic number 116.
Halogen is associated with Tennessine (Ts), with atomic number 117.
Noble gas correlates with Oganesson (Og), which has an atomic number of 118.
This alignment clarifies the classification of elements based on their family groups and chemical symbols.
From the compounds given below, number of compounds which give positive Fehling's test is _________.
Benzaldehyde, Acetaldehyde, Acetone, Acetophenone, Methanal, 4nitrobenzaldehyde, cyclohexane carbaldehyde.
Acetaldehyde $(\mathrm{CH}_3 \mathrm{CHO})$, Methanal $(\mathrm{HCHO})$, and cyclohexane carbaldehyde 
Consider the following transformation involving first order elementary reaction in each step at constant temperature as shown below.

Some details of the above reactions are listed below.
| Step | Rate constant (sec$^{-1}$) | Activation energy (kJ mol$^{-1}$) |
|---|---|---|
| 1 | $\mathrm{k_1}$ | 300 |
| 2 | $\mathrm{k_2}$ | 200 |
| 3 | $\mathrm{k_3}$ | $\mathrm{Ea_3}$ |
If the overall rate constant of the above transformation (k) is given as $\mathrm{k=\frac{k_1 k_2}{k_3}}$ and the overall activation energy $(\mathrm{E}_{\mathrm{a}})$ is $400 \mathrm{~kJ} \mathrm{~mol} \mathrm{~m}^{-1}$, then the value of $\mathrm{Ea}_3$ is ________ integer)
$\begin{aligned} & k=\frac{k_1 k_2}{k_3} \\ & E_{a_{e f f}}=E_{a_1}+E_{a_2}-E_{a_3} \end{aligned}$
$\begin{aligned} & 400=300+200-E_{\mathrm{a}_3} \\ & 400=500-E_{\mathrm{a}_3} \\ & E_{\mathrm{a}_3}=100 \mathrm{~kJ} \mathrm{~mole}^{-1} \end{aligned}$
| H_{2}CO_{3} | ⇌ | H^{+} | + | HCO_{3}^{-} | |
|---|---|---|---|---|---|
| t = 0 | 0.1 | 0 | 0 | ||
| t = t_{eq} | 0.1(1 - $\alpha $) | 0.1$\alpha $ | 0.1$\alpha $ |







